7541-02-8

Basic information

• Product Name: (Z)-2-(hydroxyimino)-2-phenylacetonitrile
• Synonyms: (Z)-2-(hydroxyimino)-2-phenylacetonitrile
• CAS NO: 7541-02-8
• Molecular Weight: 146.148
• Mol File: 7541-02-8.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: (Z)-2-(hydroxyimino)-2-phenylacetonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-2-(hydroxyimino)-2-phenylacetonitrile(7541-02-8)
• EPA Substance Registry System: (Z)-2-(hydroxyimino)-2-phenylacetonitrile(7541-02-8)

Safety Data

• Hazardous Substances Data: 7541-02-8(Hazardous Substances Data)

Upstream product

• 140-29-4 phenylacetonitrile 
• 126706-86-3 C₂₇H₃₂N₄O₆ 
• 151-50-8 potassium cyanide 
• 698-16-8 benzohydroximoyl chloride 
• 100-42-5 styrene 
• 613-90-1 benzoyl cyanide 
• 49558-03-4 4-nitro-3-phenylfuroxan 
• 372945-86-3 3-(Carbamoylmethylsulfonyl)-4-phenylfuroxan 
• 10349-06-1 3-phenylfurazan 
• 126706-88-5 C₁₈H₂₁N₃O₄ 
• 131385-62-1 4-Azido-3-phenylfurazan 2-oxide 

Downstream Products

• 126706-85-2 C₁₅H₁₇N₃O₄ 
• 126706-86-3 C₂₇H₃₂N₄O₆ 
• 7541-03-9 2-hydroxyimino-2-phenylacetonitrile 
• 126706-94-3 C₁₈H₂₃N₃O₄ 
• 126706-88-5 C₁₈H₂₁N₃O₄ 
• 69505-71-1 chlorocarbonyloxyimino-phenyl-acetonitrile 
• 1427197-16-7 tert-butyl {6-[({[(Z)-(5-oxo-4,5-dihydro-1,2,4-oxadiazol-3-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate 
• 1610354-28-3 4-(3-((3S,4R)-4-(3,4-difluorophenyl)-1-(2-methoxyethyl)pyrrolidin-3-yl)ureido)-3-phenvlisothiazole-5-carboxamide 
• 1446194-08-6 2-phenylethyl (4-{[({(2Z)-2-[ethyl(hydroxy)amino]-2-imino-1-phenylethylidene}amino)oxy]methyl}-1,3-thiazol-2-yl)carbamate 
• 1446194-12-2 2-phenylethyl {4-[({[(Z)-cyano(phenyl)methylene]amino}oxy)methyl]-1,3-thiazol-2-yl}carbamate 
• 1446193-40-3 C₂₄H₂₃N₅O₅S 
• 1446194-07-5 (2Z)-2-{[(2-bromo-1,3-thiazol-4-yl)methoxy]imino}-N-hydroxy-N-methyl-2-phenylethanimidamide 

Relevant articles and documents

Stereoselective Synthesis of (E)-2-Hydroxyimino-2-phenylacetonitrile by Photolysis of 4-Azido-3-phenylfurazan 2-Oxide

Synthesis of (E)-2-hydroxyimino-2-phenylacetonitrile from styrene was examined.This compound was obtained selectively by the photolysis of 4-azido-3-phenylfurazan 2-oxide.

Mild Synthesis of Substituted 1,2,5-Oxadiazoles Using 1,1′-Carbonyldiimidazole as a Dehydrating Agent

1,1′-Carbonyldiimidazole was found to induce the formation of a variety of 3,4-disubstituted 1,2,5-oxadiazoles (furazans) from the corresponding bisoximes at ambient temperature. This method enables these inherently energetic compounds to be prepared at t

E/Z oxime isomerism in PhC(NOH)CN

The reaction of nitric oxide with benzyl cyanide in the presence of potassium methoxide at low temperature gave the dipotassium salt of a bis-diazeniumdiolate 2 in excellent yield. Two new stereospecific syntheses of E or Z 2-(hydroxyimino)-2-phenylacetonitrile from 2 have been found. The thermodynamics of the E/Z isomerization has been investigated spectroscopically in solution, in the solid state by differential scanning calorimetry (DSC), and theoretically in the gas phase. Evidence of catalysis by NO of E/Z oxime isomerization has been observed. Copyright