75420-45-0Relevant articles and documents
A ring-closing metathesis approach to cyclic α,β-dehydroamino acids
Hekking, Koen F. W.,Waalboer, Dennis C. J.,Moelands, Marcel A. H.,Van Delft, Floris L.,Rutjes, Floris P. J. T.
supporting information; experimental part, p. 95 - 106 (2009/04/10)
A comprehensive study on the synthesis and ring-closing metathesis (RCM) of α,β-dehydroamino acids is described. This sequence has led to the formation of a range of biologically relevant functionalized nitrogen heterocycles. The incorporation of chiral b
REGIO- AND STEREOSELECTIVE HYDROGENATION OF METHYL SUBSTITUTED PENTADIEN-1-OLS BY BAKER'S YEAST
Gramatica, P.,Manitto, P.,Monti, D.,Speranza, G.
, p. 1299 - 1304 (2007/10/02)
(E)-2-methyl and (E)-3-methyl-2,4-pentadien-1-ols are reduced to (S)-2-methyl- and (S)-3-methyl-4-penten-1-ols, respectively, using baker's yeast as a regio- and stereoselective reagent.This microbiological conversion provides an efficient route to bifunctional and enantiomerically pure C6-building blocks containing the C'-CH(Me)-C'' grouping.
Stereoselective Synthesis of (S,E)-6-Isopropyl-3,9-dimethyl-5,8-decadienyl Acetate, the (S)-Enantiomer of the Yellow Scale Pheromone
Masuda, Satoru,Kuwahara, Shigefumi,Suguro, Toshio,Mori, Kenji
, p. 2515 - 2520 (2007/10/02)
The (S)-enantiomer of the sex pheromone of the yellow scale (Aonidiella citrina), (S,E)-6-isopropyl-3,9-dimethyl-5,8-decadienyl acetate, was stereoselectively synthesized from (R)-(+)-citronellic acid.