755027-18-0Relevant articles and documents
Using Nature's polyenes as templates: studies of synthetic xanthomonadin analogues and realising their potential as antioxidants
Madden, Katrina S.,Jokhoo, Hans R. E.,Conradi, Fabian D.,Knowles, Jonathan P.,Mullineaux, Conrad W.,Whiting, Andrew
supporting information, p. 3752 - 3759 (2019/04/17)
Two truncated analogues of the polyenyl photoprotective xanthomonadin pigments have been synthesised utilising an iterative Heck-Mizoroki (HM)/iododeboronation cross coupling approach and investigated as models of the natural product photoprotective agent
Active Molybdenum-Based Anode for Dehydrogenative Coupling Reactions
Beil, Sebastian B.,Müller, Timo,Sillart, Sydney B.,Franzmann, Peter,Bomm, Alexander,Holtkamp, Michael,Karst, Uwe,Schade, Wolfgang,Waldvogel, Siegfried R.
supporting information, p. 2450 - 2454 (2018/02/09)
A new and powerful active anode system that can be operated in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) has been discovered. In HFIP the molybdenum anode forms a compact, conductive, and electroactive layer of higher-valent molybdenum species. This system can replace powerful but stoichiometrically required MoV reagents for the dehydrogenative coupling of aryls. This electrolytic reaction is more sustainable and allows the conversion of a broad scope of activated arenes.
Progress Toward a Semi-Synthetic Organism with an Unrestricted Expanded Genetic Alphabet
Dien, Vivian T.,Holcomb, Matthew,Feldman, Aaron W.,Fischer, Emil C.,Dwyer, Tammy J.,Romesberg, Floyd E.
supporting information, p. 16115 - 16123 (2018/11/23)
We have developed a family of unnatural base pairs (UBPs), exemplified by the pair formed between dNaM and dTPT3, for which pairing is mediated not by complementary hydrogen bonding but by hydrophobic and packing forces. These UBPs enabled the creation of