75508-73-5Relevant articles and documents
Suzuki-Miyaura, α-ketone arylation and dehalogenation reactions catalyzed by a versatile N-heterocyclic carbene-palladacycle complex
Navarro, Oscar,Marion, Nicolas,Oonishi, Yoshihiro,Kelly III, Roy A.,Nolan, Steven P.
, p. 685 - 692 (2007/10/03)
The activity of the complex (IPr)PdCl(η2-N,C-C 12H7NMe2), 1 [IPr = (N,N′-bis(2,6- diisopropylphenyl)-imidazol)-2-ylidene], in the Suzuki-Miyaura cross-coupling reaction involving unactivated aryl chlorides and triflates with arylboronic acids at room temperature in technical grade 2-propanol is described. These conditions allow for the synthesis of di- and tri-ortho-substituted biaryls in very short reaction times. This complex also displays very high activity for α-ketone arylation and dehalogenation reactions of activated and unactivated aryl chlorides.
Well-defined, air-stable (NHC)Pd(Allyl)Cl (NHC = N-heterocyclic carbene) catalysts for the arylation of ketones
Viciu, Mihai S.,Germaneau, Romain F.,Nolan, Steven P.
, p. 4053 - 4055 (2007/10/03)
(formula presented) A number of palladium-N-heterocyclic carbene (NHC) complexes were found to be active catalysts for the arylation of ketones. A large number of substrates, both aryl halides and ketones, are compatible with the reaction conditions. The ketone arylation reactions are achieved with low catalyst loading in short reaction times using aryl chlorides and triflates as reactive partners.
Antifungal triazole ethanol derivatives
-
, (2008/06/13)
Antifungal and plant growth regulatory compounds of the formula STR1 in which R1 is alkyl, cycloalkyl or optionally substituted phenyl, and R2 is optionally substituted phenyl or benzyl.