75511-33-0Relevant articles and documents
Photosolvolysis of O,O,S-Trimethyl Phosphorodithioate. Evidence for an SN1(P) Mechanism
Benschop, Hendrik P.,Konings, Cornelis A. G.,Platenburg, Dominique H. J. M.,Deen, Rudolf
, p. 370 - 372 (2007/10/02)
Irradiation (254 nm) of (MeO)2P(S)SMe in ROH yields mainly (66 percent, R = Pri) the ionic photosolvolysis product (MeO)2P(S)OR with very low capture ratio 1.9 +/- 0.4 for R = Me vs.R = Pri under competitive photosolvolysis conditions, whereas irradiation in e.g. tetrahydrofuran and CH2Cl2 gives free-radical products, suggesting that the photoreactions proceed by way of an 'intimate radical-ion pair.'