75526-82-8Relevant articles and documents
A Facile Synthesis of 1-Oxo-1H-pyrazolopyrazol-4-ium-3-olates
Kappe, Thomas,Kos, Carlo
, p. 629 - 630 (2007/10/02)
The thermal condensation at 200-300 deg C of pyrazoles 1a-c with substituted diethyl malonates 2a-c or triethyl methanetricarboxylate 2d yields the 1-oxo-1H-pyrazolo-pyrazol-4-ium-3-olates 3a-h.
Cross-Conjugated and Psaeudo-Cross-Conjugated Mesomeric Betaines. 1. Synthesis and Characterization
Potts, Kevin T.,Murphy, Peter M.,Kuehnling, William R.
, p. 2889 - 2898 (2007/10/02)
Reaction of pyrazoles, 1,2,3-triazoles, and 1,2,4-triazoles with aryl(chlorocarbonyl)ketenes, alkylmalonyl dichlorides, or carbon suboxide results in a series of cross-conjugated mesomeric betaines, characterized by the presence of distinct cationic and anionic segments. 1-Substituted imidazoles, suitably substituted 1,2,4-triazoles, and pyridine with the above reagents give rise to pseudo-cross-conjugated mesomeric betaines which, in addition to charge separation, are characterized by the presence of the 2-oxyallyl cation 1,3-dipole.Alternative syntheses of cross-conjugated mesomeric betaines which allow the introduction of more diverse substituents are also described.
Reactions of (Chlorocarbonyl)phenylketene. Formation of a New Class of Heterocyclic Zwitterion
Potts, Kevin T.,Kanemasa, Shuji,Zvilichovsky, Gury
, p. 3971 - 3972 (2007/10/02)
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