75534-58-6Relevant articles and documents
Four-Directional synthesis of adamantane derivatives
Qu, Tao,White, Andrew J. P.,Barrett, Anthony G. M.
, p. 18 - 50 (2020/08/28)
1-Adamantanemethanol, 1,3-adamantanedimethanol and 1,3,5,7-adamantanetetramethanol were converted into adamantanes functionalized with one or four (2R,1S)-2-formyl-1-cyclopropyl residues using Charette enantioselective cyclopropanation reactions and with one, two or four 4-ethoxy- (or 4-t-butoxy)-3-diazo-2,4- dioxobutyl residues from aldehyde and diazo-acetate ester condensation reactions by 1-directional, 2- directional or 4-directional syntheses. The synthesis of adamantane fused to cyclopentadiene is also reported. 'Equation Presented'.
Chromophore Multiplication To Enable Exciton Delocalization and Triplet Diffusion Following Singlet Fission in Tetrameric Pentacene
Hetzer, Constantin,Basel, Bettina S.,Kopp, Sebastian M.,Hampel, Frank,White, Fraser J.,Clark, Timothy,Guldi, Dirk M.,Tykwinski, Rik R.
supporting information, p. 15263 - 15267 (2019/10/22)
A tetrameric pentacene, PT, has been used to explore the effects of exciton delocalization on singlet fission (SF). For the first time, triplet decorrelation through intramolecular triplet diffusion was observed following SF. Transient absorption spectros