75601-03-5

Basic information

• Product Name: 4-aminoacetophenone 2,6-dimethylphenylhydrazone
• CAS NO: 75601-03-5
• Molecular Weight: 253.347
• Mol File: 75601-03-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-aminoacetophenone 2,6-dimethylphenylhydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: 4-aminoacetophenone 2,6-dimethylphenylhydrazone(75601-03-5)
• EPA Substance Registry System: 4-aminoacetophenone 2,6-dimethylphenylhydrazone(75601-03-5)

Safety Data

• Hazardous Substances Data: 75601-03-5(Hazardous Substances Data)

Upstream product

• 99-92-3 p-aminobenzophenone 
• 603-77-0 (2,6-dimethylphenyl)hydrazine 

Downstream Products

• 75601-07-9 3-(4-amino-3,5-dimethylphenyl)-4-aminoacetophenone 
• 75601-06-8 ω-(4-amino-3,5-dimethylphenyl)-4-aminoacetophenone 
• 75601-04-6 2-(4-aminophenyl)-4,7-dimethylindole 
• 75601-05-7 2-(4-aminophenyl)-3a,5-dimethyl-3a,4,7,7a-tetrahydro-3H-pseudoindol-4-one 

Relevant articles and documents

Rearrangement of arylhydrazones of aromatic and arylaliphatic carbonyl compounds to biphenyl derivatives. 3

The behavior toward polyphosphoric acid of arylhydrazones of aromatic carbonyl compounds (anisaldehyde, substituted benzophenones, (4-methoxyphenyl)glyoxylic acid esters) and arylaliphatic ketones (4-methoxy- and 4-aminoacetophenone) is described.Biphenyl derivatives are formed through a sigmatropic rearrangement, which often occurs in competition with the expected Fischer indole synthesis and, in the case of the 4-amino-acetophenone 2,6-dimethylphenylhydrazone, with a completely new sigmatropic rearrangement.