757198-90-6Relevant articles and documents
Silicon compounds
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, (2008/06/13)
The present invention provides a silicon compound represented by Formula (1) and a polymer obtained by using the same, and this makes it possible not only to obtain an organic-inorganic composite material having a distinct structure but also to control the structure of the above polymer as a molecular aggregate. wherein R1 is a group independently selected from hydrogen, alkyl having a carbon atom number of 1 to 40, substituted or non-substituted aryl and substituted or non-substituted arylalkyl; in this alkyl having a carbon atom number of 1 to 40, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O—, —CH═CH—, cycloalkylene or cycloalkenylene; in alkylene in this arylalkyl, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O— or —CH═CH—; and A1 is a group having an α-haloester bond.
Living radical polymerization by polyhedral oligomeric silsesquioxane- holding initiators: Precision synthesis of tadpole-shaped organic/inorganic hybrid polymers
Ohno, Kohji,Sugiyama, Satoshi,Koh, Kyoungmoo,Tsujii, Yoshinobu,Fukuda, Takeshi,Yamahiro, Mikio,Oikawa, Hisao,Yamamoto, Yasuhiro,Ootake, Nobumasa,Watanabe, Kenichi
, p. 8517 - 8522 (2007/10/03)
Incompletely condensed polyhedral oligomeric silsesquioxane (POSS) with the highly reactive group of trisodium silanolate was used for the synthesis of two initiators for atom transfer radical polymerization, one with a 2-bromoisobutyl group and the other
