75748-10-6

Basic information

• Product Name: Silane, (4-chlorobenzoyl)trimethyl-
• CAS NO: 75748-10-6
• Molecular Formula: C10H13ClOSi
• Molecular Weight: 212.751
• Mol File: 75748-10-6.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Silane, (4-chlorobenzoyl)trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (4-chlorobenzoyl)trimethyl-(75748-10-6)
• EPA Substance Registry System: Silane, (4-chlorobenzoyl)trimethyl-(75748-10-6)

Safety Data

• Hazardous Substances Data: 75748-10-6(Hazardous Substances Data)

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 
• 637-87-6 1-Chloro-4-iodobenzene 
• 201230-82-2 carbon monoxide 
• 254973-56-3 2-(4-Chlorophenyl)-2-(trimethylsilyl)-1,3-dithiane 
• 122-01-0 4-chloro-benzoyl chloride 
• 76943-82-3 [Dibromo-(4-chloro-phenyl)-methyl]-trimethyl-silane 
• 10359-09-8 2-(4-chlorophenyl)-1,3-dithiane 

Downstream Products

• 144968-92-3 1-(4-Chloro-phenyl)-2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-1-trimethylsilanyl-heptan-1-ol 
• 151961-16-9 (E)-Perfluorohex-1-enyl 4-chlorophenyl ketone 
• 37542-28-2 methyl (p-chlorphenyl)glyoxylate 
• 7498-66-0 (3-chlorophenyl)(4-chlorophenyl)methanone 

Relevant articles and documents

Visible-Light-Induced Catalyst-Free Carboxylation of Acylsilanes with Carbon Dioxide

Intermolecular carbon-carbon bond formation between acylsilanes and carbon dioxide (CO2) was achieved by photoirradiation under catalyst-free conditions. In this reaction, siloxycarbenes generated by photoisomerization of the acylsilanes added to the C═O bond of CO2 to give α-ketocarboxylates, which underwent hydrolysis to afford α-ketocarboxylic derivatives in good yields. Control experiments suggest that the generated siloxycarbene is likely to be from the singlet state (S1) of the acylsilane and the addition to CO2 is not in a concerted manner.

DENTAL COMPOSITION

The present invention relates to a dental composition comprising a specific polymerization initiator system comprising a compound having an acylsilyl- or acylgermanyl-group. The present invention also relates the use of the compound having an acylsilyl- o

Synthesis of Acylsilanes via Catalytic Dedithioacetalization of 2-Silylated 1,3-Dithianes with 30% Hydrogen Peroxide

Acylsilanes were obtained efficiently from dedithioacetalization of 2-silylated 1,3-dithianes using 30% hydrogen peroxide catalyzed by iron(III) acetylacetonate-sodium iodide. The use of niobium(V) chloride as a catalyst instead of iron(III) acetylacetonate was also effective, except in synthesizing some acyltrimethylsilanes.