75825-04-6

Basic information

• Product Name: 3-Oxa-2,5-diazabicyclo[2.2.2]oct-7-ene-5-carboxylic acid, 2-phenyl-, methyl ester
• CAS NO: 75825-04-6
• Molecular Formula: C13H14N2O3
• Molecular Weight: 246.266
• Mol File: 75825-04-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-Oxa-2,5-diazabicyclo[2.2.2]oct-7-ene-5-carboxylic acid, 2-phenyl-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Oxa-2,5-diazabicyclo[2.2.2]oct-7-ene-5-carboxylic acid, 2-phenyl-, methyl ester(75825-04-6)
• EPA Substance Registry System: 3-Oxa-2,5-diazabicyclo[2.2.2]oct-7-ene-5-carboxylic acid, 2-phenyl-, methyl ester(75825-04-6)

Safety Data

• Hazardous Substances Data: 75825-04-6(Hazardous Substances Data)

Upstream product

• 33707-36-7 1-(methoxycarbonyl)-1,2-dihydropyridine 
• 586-96-9 Nitrosobenzene 

Downstream Products

• 83022-22-4 7,8-dihydroxy-2-phenyl-3-oxa-2,5-diazabicyclo<2.2.2>octane-5-carboxylate 
• 83022-23-5 4,5-dideoxy-5-(methoxycarbonyl)amino-4-(phenylamino)-αβ-DL-lyxopyranose 
• 83022-24-6 (2R,3S,4S,5R)-3,4-Dihydroxy-2-methoxy-5-phenylamino-piperidine-1-carboxylic acid methyl ester 

Relevant articles and documents

A FACILE THREE-STEP SYNTHESIS OF A RACEMIC 4,5-DIAMINO-4,5-DIDEOXY-α-D,β-L-LYXOPYRANOSE.

Diels-Alder cycloaddition of nitrosobenzene to 1-methoxycarbonyl-1,2-dihydropyridine led in high yield to the endocyclic hydroxylamine adduct 5.which was successively oxydized with potassium permanganate and hydrogenolyzed to give the new aminosugar 4,5-d

Diels-Alder cycloadditions of N-substituted-1,2-dihydropyridines with nitrosobenzene. Synthesis of 3-phenyl-2-oxa-3,6-diazabicyclooct-7-enes

The regiospecific (?2 + ?4) cycloaddition reaction of N-carbonyl-1,2-dihydropyridines 2 with nitrosobenzene afford a mixture of 3-phenyl-2-oxa-3,6-diazabicyclooct-7-ene rotamers 3 and 4.Rotamers 3 and 4, which differ in configuration at the carbony