75937-76-7Relevant articles and documents
REACTION OF SULFUR HALIDES WITH UNSATURATED COMPOUNDS XV. 2,2'-DICHLORO SULFIDES IN REACTION WITH ORGANOALUMINUM COMPOUNDS
Tolstikov, G. A.,Kantyukova, R. G.,Spirikhin, L. V.
, p. 1210 - 1218 (2007/10/02)
The reaction of 2,2'-dichloro sulfides with organoaluminum compounds was investigated.The reaction leads to dechlorination or alkylation products, depending on the structure of the organoaluminum compounds.It was established that nickel, titanium, and zirconium compounds have catalytic activity and enabled the reactions to occur under milder conditions.The addition of sulfur dichloride to 1-methyl- and 1,5-dimethyl-1,5-cyclooctadienes was investigated, and the rearrangement was followed in the series of 9-thiabicyclononane derivatives.