76002-40-9Relevant articles and documents
Copper-catalyzed allylic C-H phosphonation
Yang, Bin,Zhang, Hong-Yu,Yang, Shang-Dong
supporting information, p. 3561 - 3565 (2015/03/30)
An efficient copper-catalyzed allylic C-H phosphonation reaction has been developed under mild reaction conditions. This method exhibits high regioselectivity and stereoselectivity. Various alkenes with useful functional groups are compatible in this tran
STEREOCHEMICALLY CONTROLLED SYNTHESIS OF UNSATURATED ACIDS VIA DIPHENYLPHOSPHINOYL(Ph2PO)-KETOACIDS
Levin, Daniel,Warren, Stuart
, p. 505 - 508 (2007/10/02)
Acylation of phosphine oxide anions with derivatives of cyclic anhydrides or oxidative cleavage of cyclic allyl phosphine oxides gives Ph2PO-ketoacids: reduction, separation of diastereoisomers, and completion of the Horner-Wittig reaction gives single isomers (E or Z) of unsaturated acids.
Synthesis of an Unstable Allyl Sulphide from an Allyl Phosphine Oxide
Torr, Richard S.,Warren, Stuart
, p. 1169 - 1172 (2007/10/02)
The epoxide (8) reacts with PhSLi to give Horner-Wittig intermediate (9) and hence the allyl sulphide (10).The stereochemistry and reactions of the intermediates are described.
