76071-61-9

Basic information

• Product Name: 5-Nonanol, 5-(2-propenyl)-
• CAS NO: 76071-61-9
• Molecular Formula: C12H24O
• Molecular Weight: 184.322
• Mol File: 76071-61-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-Nonanol, 5-(2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Nonanol, 5-(2-propenyl)-(76071-61-9)
• EPA Substance Registry System: 5-Nonanol, 5-(2-propenyl)-(76071-61-9)

Safety Data

• Hazardous Substances Data: 76071-61-9(Hazardous Substances Data)

Upstream product

• 249894-59-5 3,3-Dibutyl-1,2,4-trioxaspiro[5.4]decane 
• 762-72-1 allyl-trimethyl-silane 

Downstream Products

• 502-56-7 nonanone-5 

Relevant articles and documents

Selectivity in Lewis acid-mediated fragmentations of peroxides and ozonides: Application to the synthesis of alkenes, homoallyl ethers, and 1,2-dioxolanes

Fragmentation of dialkyl peroxides and ozonides is strongly influenced by the choice of Lewis acid. TiCl4 promotes C-O ionization (SN1 reaction) of tertiary peroxides while SnCl4 and BF3·OEt2 promote O-O heterolysis (Hock reaction). The cationic intermediates are trapped with allyltrimethylsilane to afford allylated alkanes and homoallyl ethers. In the absence of a nucleophile, ozonides (1,2,4-trioxolanes) invariably undergo O-O heterolysis. However, the combination of allyltrimethylsilane and SnCl4 results in formation of 1,2-dioxolanes via trapping of intermediates derived from SN1 ionization.