76136-93-1

Basic information

• Product Name: (ethylene)bis(triethylphosphine)platinum⁽⁰⁾
• Synonyms: (ethylene)bis(triethylphosphine)platinum⁽⁰⁾
• CAS NO: 76136-93-1
• Molecular Weight: 459.451
• Mol File: 76136-93-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (ethylene)bis(triethylphosphine)platinum⁽⁰⁾(CAS DataBase Reference)
• NIST Chemistry Reference: (ethylene)bis(triethylphosphine)platinum⁽⁰⁾(76136-93-1)
• EPA Substance Registry System: (ethylene)bis(triethylphosphine)platinum⁽⁰⁾(76136-93-1)

Safety Data

• Hazardous Substances Data: 76136-93-1(Hazardous Substances Data)

Upstream product

• 74-85-1 ethene 
• 1352241-85-0 cis-[Pt(H)(Si(OEt)3)(PEt₃)2] 
• 1352241-85-0 trans-[Pt(H)(Si(OEt)3)(PEt₃)2] 
• 75847-39-1 diethylbis(triethylphosphine)platinum(II) 

Relevant articles and documents

Si-H and Si-Si activation at Pt: Synthesis and reactivity of neutral and cationic silyl complexes

Reactions of [Pt(PEt3)3] (1) with the silanes HSiPh3, HSiPh2Me and HSi(OEt)3 led to the products of oxidative addition, cis-[Pt(H)(SiPh3)(PEt 3)2] (2), cis-[Pt(H)(SiPh2Me)(PEt 3)2] (3), cis-[Pt(H){Si(OEt)3}(PEt 3)2] (cis-4) and trans-[Pt(H){Si(OEt)3} (PEt3)2] (trans-4). The complexes cis-4 and trans-4 can also be generated by hydrogenolysis of (EtO)3SiSi(OEt)3 in the presence of 1. Furthermore, the silyl compounds cis-4 and trans-4 react with B(C6F5)3 and CH3CN by hydride abstraction to give the cationic silyl complex trans-[Pt{Si(OEt) 3}(NCCH3)(PEt3)2][HB(C 6F5)3] (8). In addition, the reactivity of the complexes cis-4, trans-4 and 8 towards alkenes and CO was studied using NMR experiments.