76192-88-6Relevant articles and documents
Stereospecific synthesis of the fungal prohormone (±)-trisporol B via the palladium-catalyzed cross-coupling reaction of 1-alkenylborane with 1-haloalkene
Miyaura,Satoh,Hara,Suzuki
, p. 2029 - 2031 (1986)
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PROCESS FOR PRODUCING CYCLOHEXENONE LONG-CHAIN ALCOHOLS
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Page 8-9, (2010/02/08)
A process for producing cyclohexenone long-chain alcohol represented by the following formula (1): (wherein A represents a C10-C18 alkylene or alkenylene group, and each of R1, R2, and R3 individually represents hydrogen o
Total Synthesis of (+/-)-Isocomene and Related Studies
Pirrung, Michael C.
, p. 82 - 87 (2007/10/02)
The total synthesis of the tricyclic sesquiterpene isocomene is described.The key bond forming reaction involves an intramolecular photocyloaddition to give tricyclo1,6>undecanone 6.Two routes are described from 6 to isocomene.The first involves acid-catalyzed rearrangement to tricyclo1,5>undecanone 7, addition of MeLi, and solvolysis, while the second uses a Wittig reaction followed by acid-catalyzed rearrangement.The question of maximum continuous orbital overlap in cyclobutyl carbinyl cation rearrangements is discussed, and certain stereochemical effects are found.