7623-25-8

Basic information

• Product Name: 2-methyl-3-oxa-1,5-hexadiene
• Synonyms: 2-methyl-3-oxa-1,5-hexadiene
• CAS NO: 7623-25-8
• Molecular Weight: 98.1448
• Mol File: 7623-25-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-methyl-3-oxa-1,5-hexadiene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-3-oxa-1,5-hexadiene(7623-25-8)
• EPA Substance Registry System: 2-methyl-3-oxa-1,5-hexadiene(7623-25-8)

Safety Data

• Hazardous Substances Data: 7623-25-8(Hazardous Substances Data)

Upstream product

• 87384-19-8 2-ethoxy-2-allyloxy-propane 
• 107-18-6 allyl alcohol 
• 77-76-9 2,2-dimethoxy-propane 
• 35219-73-9 2,2-bis-allyloxy-propane 
• 104-15-4 toluene-4-sulfonic acid 

Downstream Products

• 109-49-9 5-Hexen-2-one 
• 2057-91-2 hex-5-en-2-one-(2,4-dinitro-phenylhydrazone) 

Relevant articles and documents

The Convergent Synthesis of Polyether Ionophore Antibiotics: An Approach to the Synthesis of the Monensin Tetrahydropyran-Bis(tetrahydrofuran) via the Ester Enolate Claisen Rearrangement and Reductive Decarboxylation

The monensin tetrahydropyran equivalent 22 is prepared from D-fructose and then joined to the monensin bis(tetrahydrofuran) equivalent 24a via the ester enolate Claisen rearrangement.Methodology for the radical induced, reductive decarboxylation of the resulting acid 26a is described.Anomeric stabilization of the intermediate tetrahydrofuran-2-yl radical is an important factor in the stereochemical outcome of this process.Reduction of 1-chloro-2,3-O-isopropylidene furanoid and pyranoid carbohydrate derivatives with lithium di-tert-butylbiphenyl affords the corresponding glycals in high yield.