76355-29-8

Basic information

• Product Name: 3-(phenylsulfonyl)bicyclo[2.2.2]octane
• Synonyms: 3-(phenylsulfonyl)bicyclo[2.2.2]octane
• CAS NO: 76355-29-8
• Molecular Weight: 250.362
• Mol File: 76355-29-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-(phenylsulfonyl)bicyclo[2.2.2]octane(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(phenylsulfonyl)bicyclo[2.2.2]octane(76355-29-8)
• EPA Substance Registry System: 3-(phenylsulfonyl)bicyclo[2.2.2]octane(76355-29-8)

Safety Data

• Hazardous Substances Data: 76355-29-8(Hazardous Substances Data)

Upstream product

• 77550-13-1 (1S,4S)-5-Benzenesulfonyl-bicyclo[2.2.2]oct-2-ene 
• 92865-78-6 3-(phenylthio)bicyclo[2.2.2]octane 
• 108-98-5 thiophenol 
• 931-64-6 norbornene 

Downstream Products

• 2716-23-6 Bicyclo<2.2.2>octan-2-one 
• 77508-50-0 2-(Phenylsulfonyl)-2-(trimethylsilyl)bicyclo<2.2.2>octane 

Relevant articles and documents

Experimental evidence for negative hyperconjugation as a component of the polar effect: Variation of the ease of α-sulfonyl carbanion formation with the orientation of a β-alkoxy substituent

We report evidence for a strongly geometry-dependent substituent effect. The rate constants for H-D exchange of the α-hydrogens, (k(exch))OR, in a set of 19 β-alkoxy sulfones of known, fixed (or strongly preferred) H-C(α)-C(β)-OR torsion angles have been