76361-99-4

Basic information

• Product Name: 3-Bromo-2-nitrophenol
• Synonyms: 3-Bromo-2-nitrophenol 99%;2-Bromo-6-hydroxynitrobenzene;3-Bromo-2-nitrophenol96%;Phenol, 3-bromo-2-nitro-;3-BROMO-2-NITROPHENOL
• CAS NO: 76361-99-4
• Molecular Formula: C₆H₄BrNO₃
• Molecular Weight: 218
• Mol File: 76361-99-4.mol
• Article Data: 1

Chemical Properties

• Melting Point: 65-67 °C
• Boiling Point: 234.4 °C at 760 mmHg
• Flash Point: 95.6 °C
• Appearance: /
• Density: 1.881 g/cm³
• Vapor Pressure: 0.0346mmHg at 25°C
• Refractive Index: 1.651
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 4.49±0.10(Predicted)
• CAS DataBase Reference: 3-Bromo-2-nitrophenol(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Bromo-2-nitrophenol(76361-99-4)
• EPA Substance Registry System: 3-Bromo-2-nitrophenol(76361-99-4)

Safety Data

• Hazardous Substances Data: 76361-99-4(Hazardous Substances Data)

Usage

Chemical Properties

Light yellow crystalline

InChI:InChI=1/C6H4BrNO3/c7-4-2-1-3-5(9)6(4)8(10)11/h1-3,9H

Upstream product

• 591-20-8 3-Bromophenol 
• 7664-93-9 sulfuric acid 
• 7697-37-2 nitric acid 
• 577-19-5 2-nitrophenyl bromide 

Downstream Products

• 858832-42-5 2,3,4-tribromo-6-nitro-phenol 
• 60287-37-8 1-methoxy-2-nitro-3-o-tolyloxy-benzene 
• 60287-20-9 2-(3-methoxy-2-nitro-phenoxy)-benzoic acid 
• 857539-43-6 2-(3-methoxy-2-nitro-phenoxy)-benzoic acid methyl ester 
• 725714-49-8 3,4,6-tribromo-2-nitro-anisole 
• 10199-87-8 2,4-dinitro-1,3-phenylenediamine 
• 519-44-8 2,4-dinitroresorcinol 
• 500298-30-6 2-bromo-6-methoxynitrobenzene 
• 116632-22-5 3-bromo-2,6-dinitro-phenol 
• 116632-21-4 3-bromo-2,4-dinitro-phenol 
• 815578-59-7 3,4,6-tribromo-2-nitro-phenol 
• 116435-77-9 2-amino-3-bromophenol 
• 19046-86-7 3-bromo-2,4,6-trinitro-phenol 

Relevant articles and documents

REACTION OF AROMATIC COMPOUNDS WITH NUCLEOPHILIC REAGENTS IN LIQUID AMMONIA. XIII. DIRECTION OF HYDROXYLATION OF 2-HALONITROBENZENES BY POTASSIUM HYDROXIDE

The reaction of 2-fluoronitrobenzene with potassium hydroxide and molecular oxygen in liquid ammonia at -33 deg C gave 2-nitrophenol.In contrast to 2-fluoronitrobenzene, both the halogen and hydrogen in the ortho and para positions to the nitro group are replaced in the reactions of 2-chloro- and 2-bromonitrobenzenes, KOH, and O2.In the case of 2-bromonitrobenzene, there is significant formation of a compound, formally corresponding to reductive dehalogenation (nitrobenzene and its hydroxylation product, 4-nitrophenol) and bromination of the nitrophenols formed in the position to the hydroxy group.