76372-46-8

Basic information

• Product Name: 1-acetoxy-4-acetylsulfanyl-benzene
• Synonyms: 1-acetoxy-4-acetylsulfanyl-benzene
• CAS NO: 76372-46-8
• Molecular Weight: 210.254
• Mol File: 76372-46-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-acetoxy-4-acetylsulfanyl-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-acetoxy-4-acetylsulfanyl-benzene(76372-46-8)
• EPA Substance Registry System: 1-acetoxy-4-acetylsulfanyl-benzene(76372-46-8)

Safety Data

• Hazardous Substances Data: 76372-46-8(Hazardous Substances Data)

Usage

Physical state

Colorless to pale yellow liquid

Odor

Potent, sweet, fruity

Usage

Production of flavor and fragrance products

Application

Synthetic intermediate in manufacturing of pharmaceuticals, dyes, and perfumes

Industry

Food and beverage industry for flavor and aroma enhancement

Safety precautions

Harmful if ingested or inhaled, may cause skin and eye irritation

Handling

Handle with caution, use appropriate protective equipment

Upstream product

• 33527-94-5 4-acetoxyiodobenzene 
• 10387-40-3 potassium thioacetate 
• 62262-76-4 carbonic acid ethyl ester-(4-mercapto-phenyl ester) 
• 60852-04-2 4-t-Butoxyophenyl-t-butylsulfid 
• 75-36-5 acetyl chloride 
• 637-89-8 4-sulfanylphenol 
• 108-24-7 acetic anhydride 

Downstream Products

• 15015-57-3 bis(4-hydroxyphenyl)disulfide 

Relevant articles and documents

NiNP@rGO Nanocomposites as Heterogeneous Catalysts for Thiocarboxylation Cross-Coupling Reactions

A new type of ligand-free Ni-nanoparticles supported on rGO (size distribution average d = 9 ± 3 nm) was prepared and fully characterized via morphological (Fe-SEM), structural (P-XRD, HR-TEM), and spectroscopic (ICP-EOS, XPS) analysis tools. The metal composite was effectively employed in the unprecedented heterogeneously Ni-assisted cross-coupling reaction of aryl/vinyl iodides and thiocarboxylates. A range of sulfur-containing aryl as well as vinyl derivatives (15 examples) was achieved in high yields (up to 82%), under mild reaction conditions, and with wide functional group tolerance.

Silica-supported boric acid catalyzed synthesis of dihydropyrimidin-2-ones, bis(indolyl)methanes, esters and amides

Silica-supported boric acid (H3BO3-SiO2) has been established as a green, efficient and recyclable catalyst for the synthesis of dihydropyrimidin-2-ones, bis(indolyl)methanes, and acetylation of alcohols, phenols, amines and thiols under solvent free conditions. The main features of the present method include clean reaction, mild conditions, low loading of environment friendly catalyst and easy workup procedure. The catalyst can be recycled at least five times without any significant loss in activity.

Bromine catalyzed conversion of S-tert-butyl groups into versatile and, for self-assembly processes accessible, acetyl-protected thiols

The facile and efficient conversion of a tert-butyl protecting group to an acetyl protecting group for thiols by catalytic amounts of bromine in acetyl chloride and the presence of acetic acid has been developed. The fairly mild reaction conditions are of