76460-87-2Relevant articles and documents
Nickel-catalyzed sp3 C-H bond activation from decarboxylative cross-coupling of α,β-unsaturated carboxylic acids with amides
Zhang, Jia-Xiang,Wang, Yan-Jing,Wang, Nai-Xing,Zhang, Wei,Bai, Cui-Bing,Li, Yi-He,Wen, Jia-Long
, p. 1621 - 1625 (2014/07/08)
Nickel-catalyzed functionalization of C(sp3)-H bonds adjacent to a nitrogen atom in amides through decarboxylative cross-coupling of α,β-unsaturated carboxylic acids is reported. A possible reaction mechanism is proposed that involves radical intermediate species. Georg Thieme Verlag Stuttgart, New York.
Electroorganic Chemistry. 46. A New Carbon-Carbon Bond Forming Reaction at the α-Position of Amines Utilizing Anodic Oxidation as a Key Step
Shono, Tatsuya,Matsumura, Yoshihiro,Tsubata, Kenji
, p. 1172 - 1176 (2007/10/02)
A new carbon-carbon bond forming reaction at the α-position of primary and secondary amines has been exploited.The method involves anodic oxidation of urethanes derived from the primary and secondary amines and subsequent acid-catalyzed reaction of the re