764696-71-1Relevant articles and documents
Influence of substitution at the 5α-Position on the side chain conformation of glucopyranosides
Rajasekaran, Parasuraman,Pirrone, Michael G.,Crich, David
, (2021)
We describe the preparation of methyl 5α-methyl-α-D-glucopyranoside and of 5α-fluoro-β-D-glucopyranose per acetate and the NMR-based conformational analysis of their side chains. Both the 5α-methyl and 5α-fluoro substituents increase the population of the