765-17-3Relevant articles and documents
Bidirectional, organocatalytic synthesis of lepidopteran sex pheromones
De Figueiredo, Renata Marcia,Berner, Raphael,Julis, Jennifer,Liu, Ting,Tuerp, David,Christmann, Mathias
, p. 640 - 642 (2007/10/03)
Shuffling of two simple building blocks and a regioselective transfer hydrogenation allow for the rapid synthesis of a small collection of lepidopteran sex pheromones, e.g., 8E,10Z-tetradeca-8,10-dienal 5c, from the horse chestnut leafminer (Cameraria ohridella).
A facile preparation of geometrically pure alkenyl, alkynyl, and aryl conjugated Z-alkenes: Stereospecific synthesis of bombykol
Uenishi, Jun'Ichi,Kawahama, Reiko,Izaki, Yoshiyuki,Yonemitsu, Osamu
, p. 3493 - 3500 (2007/10/03)
Ni- and Pd-catalyzed cross coupling reactions of 2-alkenyl, 2-alkynyl, and 2-aryl substituted (1Z)-1-bromoalkene with alkyl Grignard reagents gave 1-alkyl substituted (1Z,3E)-diene, (1Z)-en-3-yne, and (1Z)-2-arylethene, each in good yield. When (trimethylsilyl)-methylmagnesium chloride was used as the Grignard reagent, conjugated Z-allylsilane was produced. Bombykol, (10E, 12Z)-10,12-hexadecadien-1-ol, a sex pheromone of female moss, Bombyx mori, was synthesized stereospecifically. 2000 Elsevier Science Ltd.
Alkene ozonolysis and the study of reactions of polyfunctional compounds: LXI. New synthetic route to bombycol, pheromone of mulberry silkworm
Kukovinets,Kasradze,Chernukha,Odinokov,Dolidze,Galin,Spirikhin,Abdullin,Tolstikov
, p. 1156 - 1159 (2007/10/03)
Starting from a product of partial ozonolysis of 1,4-cyclohexadiene, methyl (E)-6-oxo-4-hexenoate, a new synthetic route was developed for (10E, 12Z)-hexadeca-10,12-dien-1-ol (bombycol), the main component of sex pheromone of mulberry silkworm (Bombix mori).