76580-08-0Relevant articles and documents
Catalytic α-Arylation of Ketones with Heteroaromatic Esters
Isshiki, Ryota,Takise, Ryosuke,Itami, Kenichiro,Muto, Kei,Yamaguchi, Junichiro
supporting information, p. 2599 - 2603 (2017/10/31)
Heteroaromatic esters were found to be applicable as an arylating agent for the Pd-catalyzed α-arylation of ketones in a decarbonylative fashion. The use of our in-house ligand, dcypt, enabled this unique bond formation. Considering the ubiquity and low cost of aromatic esters, the present work will allow for rapid access to valuable α-aryl carbonyl compounds.
LIGAND, NICKEL COMPLEX COMPRISING LIGAND, AND REACTION USING NICKEL COMPLEX
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Paragraph 0282; 0284; 0285, (2016/10/07)
PROBLEM TO BE SOLVED: To provide a method for directly carrying out arylation, especially α-arylation, of a carbonyl compound or a thiocarbonyl compound by using a more inexpensive phenol derivative and a nickel catalyst, and to provide a novel nickel cat