76591-83-8Relevant articles and documents
Bipolar hosts and non-doped deep-blue emitters (CIE: Y = 0.04) based on phenylcarbazole and 2-(2-phenyl-2 H -1,2,4-triazol-3-yl)pyridine groups
Xu, Huixia,Sun, Peng,Wang, Kexiang,Li, Jie,Wang, Fang,Miao, Yanqin,Wang, Hua,Xu, Bingshe,Wong, Wai-Yeung
, p. 4455 - 4462 (2017)
We have designed and synthesized four bipolar materials, TAZ-1Cz, TAZ-2Cz, TAZ-3Cz and TAZ-4Cz, using 2-(2-phenyl-2H-1,2,4-triazol-3-yl)pyridine (TAZ) as an electron-withdrawing group and phenylcarbazole as an electron-donating group. Their rigid molecular structures improve their thermal stability with high glass transition temperatures: 99 °C for TAZ-2Cz, 100 °C for TAZ-3Cz and 103 °C for TAZ-4Cz. Employing TAZ-1Cz, TAZ-2Cz, TAZ-3Cz and TAZ-4Cz as hosts, green phosphorescent organic light-emitting devices (PhOLEDs) with fac-tris(2-phenylpyridine)iridium as an emitter display maximum external quantum efficiencies (EQEs) of 15.8, 15.5, 16.0 and 13.0%, respectively. And blue PhOLEDs hosted by TAZ-1Cz, TAZ-2Cz and TAZ-3Cz achieved maximum current efficiencies of 8.6, 11.0 and 10.6 cd A-1, respectively. Furthermore, non-doped OLEDs using TAZ-1Cz and TAZ-4Cz as emitters exhibit electroluminescence (EL) peaks at 400 and 412 nm with CIE coordinates of (0.16, 0.04) and (0.15, 0.04), which are located in the deep-blue region.
1,2,4-Triazole acceptor-based thermally activated delayed fluorescence material
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, (2017/09/01)
The invention discloses a 1,2,4-riazole acceptor-based thermally activated delayed fluorescence material with the structure represented by general formula (I) and capable of realizing dark blue lights. The material is formed through connecting the para-position of 3-substituted phenyl group of a 1,2,4-triazole derivative used as an acceptor unit with an N-containing donor unit. The thermally activated delayed fluorescence material has small singlet-triplet energy level difference, can meet requirements of the thermally activated delayed fluorescence material, allows a dark blue fluorescence material to be obtained, and improves the luminous efficiency of TADF type OLED devices.
A novel high-efficiency white hyperbranched polymer derived from polyfluorene with green and red iridium(III) complexes as the cores
Sun, Jing,Wang, Hua,Xu, Huixia,Zhang, Tiaomei,Li, Lu,Li, Jie,Wu, Yuling,Xu, Bingshe,Zhang, Xinwen,Lai, Wenyong
, p. 191 - 201 (2016/04/05)
A new kind of single triple-color hyperbranched polymer PF-Ir(ppy)2(pytzph)m-Ir(piq)2(pytzph)n was designed and synthesized, in which green and red iridium(III) complexes acted as cores and blue polyfluorene acted as backbone. PF-Ir(ppy)2(pytzph)m-Ir(piq)2(pytzph)n (m = 5, n = 5 and m = 25, n = 5) had higher quantum efficiency than PF-Ir(piq)2(pytzph)5. The energy transfer from green core bis(2-phenylpyridine)[3-(2-pyridyl)-5-phenyl-1,2,4-triazole]iridium(III) [Ir(ppy)2(pytzph)] with high triplet energy level (ET = 2.58 eV) to red core bis(1-phenylisoquinolinato)[3-(2-pyridyl)-5-phenyl-1,2,4-triazole]iridium(III) [Ir(piq)2(pytzph)] (ET = 2.12 eV) could realize by intermediate poly(9,9-dioctylfluorene) (PF) segments. A typical single emitting-layer device with the configuration of ITO/PEDOT:PSS (40 nm)/PF-Ir(ppy)2(pytzph)m-Ir(piq)2(pytzph)n (80 nm)/TPBi (40 nm)/LiF (0.8 nm)/Al (100 nm) was fabricated. Among the white polymers, PF-Ir(ppy)2(pytzph)5-Ir(piq)2(pytzph)5 exhibited excellent electroluminescent properties with a Commission Internationale Ed I'eclairage (CIE) coordinate of (0.32, 0.34) and a maximum luminous efficiency of 11.49 cd/A.
