766-20-1Relevant articles and documents
Method for preparing 1, 3-butanediol
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Paragraph 0061-0063; 0067-0070; 000074; 0077, (2020/11/22)
The invention provides a method for preparing 1, 3-butanediol. The method comprises the following steps: (1) carrying out condensation cyclization reaction on butadiene, water and an aldehyde ketone compound according to a certain material ratio in the presence of hydrogen peroxide and a catalyst A to obtain a reaction solution containing an intermediate I; and (2) mixing the reaction solution containing the intermediate I with a certain amount of water, and carrying out hydrolysis reaction in the presence of a catalyst B to obtain 1, 3-butanediol and a corresponding aldehyde ketone compound.Compared with the existing production method, the method has the advantages of accessible reaction raw materials, high reaction conversion rate, high selectivity and the like, and is suitable for industrial production.
Reactivity of primary and secondary alcohols in nucleophilic addition to a triple bond: The vinylation of butane-1,3-diol
Oparina,Parshina,Ushakov,Shaikhudinova,Trofimov
, p. 2347 - 2349 (2007/10/03)
Acetylene adds to butane-1,3-diol in the presence of KOH to give, along with the corresponding divinyl ether and 2,4-dimethyl-1,3-dioxane, 4-vinyloxybutan-2-ol and its structural isomer 3-vinyloxybutan-1-ol, the ratio between the latter two products, (5 - 8) : 1, depending on the reaction conditions.
COBALT (II) CHLORIDE CATALYSED ADDITION OF ALCOHOLS ON VINYL ETHERS: A CONVENIENT SYNTHESIS OF MIXED ACETALS
Igbal, Javed,Srivastava, Rajeev Ranjan,Gupta, Kiran Bala,Khan, M. Amin
, p. 901 - 906 (2007/10/02)
Hydroxyl compounds readily add to Vinyl ethers in presence of a catalytic amount of Cobalt (II) Chloride, to give high yields of mixed acetals.