766-94-9Relevant articles and documents
The phenyl vinyl ether–methanol complex: A model system for quantum chemistry benchmarking
Bernhard, Dominic,Dietrich, Fabian,Fatima, Mariyam,Pérez, Cristóbal,Gottschalk, Hannes C.,Wuttke, Axel,Mata, Ricardo A.,Suhm, Martin A.,Schnell, Melanie,Gerhards, Markus
, p. 1642 - 1654 (2018)
The structure of the isolated aggregate of phenyl vinyl ether and methanol is studied by combining a multi-spectroscopic approach and quantum-chemical calculations in order to investigate the delicate interplay of noncovalent interactions. The complementa
Synthesis of vinyl phenyl ether and its use for ammetric titration of silver(I)
Nurmanov,Gevorgyan,Matmuratov,Kasimova,Sirlibaev,Kalyadin
, p. 480 - 482 (2002)
Catalytic vinylation of phenol with acetylene at atmospheric pressure was studied. The yield of vinyl phenyl ether was determined as influenced by the solvent, reaction temperature, and catalyst amount. The mechanism of formation of vinyl phenyl ether was proposed. Ammetric titration of silver(I) with a solution of vinyl phenyl ether in nonaqueous acetic acid solutions was performed.
Reusable rhodium catalyst for the selective transvinylation of sp2-C linked carboxylic acid
Jiang, Ruihang,Chen, Zhangpei,Zhan, Kun,Liu, Lei,Zhou, Junjie,Ai, Yongjian,Li, Shuang,Bao, Hongjie,Hu, Ze'nan,Qi, Li,Wang, Jingting,Sun, Hong-bin
, p. 3279 - 3282 (2018/07/21)
The vinyl benzoate derivatives were successfully synthesized by the transvinylation reactions that vinyl group transferred from vinyl acetate to aromatic carboxylic acids with the recoverable catalyst RhCl3·3H2O. This catalyst features air stable and tolerance of water, good reusable ability, meanwhile, shows high selectivity for aromatic carboxylic acid in the presence of phenolic hydroxyl. With this method, a variety of vinyl benzoate derivatives can be produced with up to 95% yield.
Direct vinylation of natural alcohols and derivatives with calcium carbide
Teong, Siew Ping,Chua, Ariel Yi Hui,Deng, Shiyun,Li, Xiukai,Zhang, Yugen
supporting information, p. 1659 - 1662 (2017/06/07)
Vinyl ethers are essential synthetic building blocks for organic synthesis, especially for polymer synthesis and highly vinylated polyol substrates. Herein, a transition metal-free, mild, and safe protocol has been developed for direct vinylation of natural alcohols with calcium carbide. Various sugar alcohols, phenol and its derivatives were tested and proved successful using this green methodology. Selectivity of full vinylated products of the reaction decreases with increasing hydroxyl groups because of side reactions occurring under the basic medium. Electron-donating substituted phenols work more efficiently than electron-withdrawing substituted phenols in general. This methodology may provide new insights on selective vinylation of electron-rich biomass-derived materials.