76691-75-3

Basic information

• Product Name: N-benzylundec-10-en-1-amine
• Synonyms: N-benzylundec-10-en-1-amine
• CAS NO: 76691-75-3
• Molecular Weight: 259.435
• Mol File: 76691-75-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: N-benzylundec-10-en-1-amine(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzylundec-10-en-1-amine(76691-75-3)
• EPA Substance Registry System: N-benzylundec-10-en-1-amine(76691-75-3)

Safety Data

• Hazardous Substances Data: 76691-75-3(Hazardous Substances Data)

Upstream product

• 76691-55-9 N-benzylundec-10-enamide 
• 112-38-9 10-undecenoic acid 
• 38460-95-6 undec-10-enoyl chloride 
• 100-46-9 benzylamine 
• 100-52-7 benzaldehyde 
• 62595-52-2 undec-10-en-1-amine 
• 112-45-8 10-Undecenal 

Relevant articles and documents

A General and Selective Rhodium-Catalyzed Reduction of Amides, N-Acyl Amino Esters, and Dipeptides Using Phenylsilane

This article describes a selective reduction of functionalized amides, including N-acyl amino esters and dipeptides, to the corresponding amines using simple [Rh(acac)(cod)]. The catalyst shows excellent chemoselectivity in the presence of different sensitive functional moieties. A selective reduction of functionalized amides, including N-acyl amino esters and dipeptides, to the corresponding amines using simple [Rh(acac)(cod)] is described (see scheme). The catalyst shows excellent chemoselectivity in the presence of different sensitive functional moieties. Even the selective reduction of a secondary amide bond in the presence of a ketone is possible.

Synthesis of medium and large cyclic amines in rhodium-catalysed reactions of aminoalkenes with H2/CO1

Rhodium-catalysed reactions of N-benzyl- or N-alkyl-aminoalkenes (6) with H2/CO can give cyclic amines (7) (7-13 ring size) in good to excellent yields when BIPHEPHOS is used as a ligand. Hydrogenation of the aminoalkene becomes a competing reaction for the smaller rings but can be overcome by using a H2/CO gas ratio of 1:5. Reactions of 2-alkenyloxybenzylamines (13) gave 9-, 12- and 17-membered rings (14) in 30-40% yield, but dimer formation (16) and/or hydrogenation were competing reactions. Similar reactions of alkenylamides and ortho-alkenylanilines gave only non-cyclized amino aldehydes as products in low isolated yields.