767222-91-3

Basic information

• Product Name: 5-METHYL-2-(4-METHYLPHENOXY)ANILINE
• Synonyms: 5-METHYL-2-(4-METHYLPHENOXY)ANILINE
• CAS NO: 767222-91-3
• Molecular Formula: C₁₄H₁₅NO
• Molecular Weight: 213.275
• Mol File: 767222-91-3.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 5-METHYL-2-(4-METHYLPHENOXY)ANILINE(CAS DataBase Reference)
• NIST Chemistry Reference: 5-METHYL-2-(4-METHYLPHENOXY)ANILINE(767222-91-3)
• EPA Substance Registry System: 5-METHYL-2-(4-METHYLPHENOXY)ANILINE(767222-91-3)

Safety Data

• Hazard Codes: Xi
• HazardClass: IRRITANT
• Hazardous Substances Data: 767222-91-3(Hazardous Substances Data)

Upstream product

• 106-44-5 p-cresol 
• 1579-40-4 1,1'-oxybis(4-methyl-benzene) 
• 1192-96-7 potassium p-cresolate 
• 5326-34-1 4-Bromo-3-nitrotoluene 
• 106-38-7 para-bromotoluene 
• 89-60-1 1-chloro-4-methyl-2-nitro-benzene 
• 150-76-5 4-methoxy-phenol 
• 2236-38-6 4-Methyl-1-(4-methylphenoxy)-2-nitrobenzene 

Downstream Products

• 2236-41-1 2-iodo-4-methyl-1-(p-tolyloxy)benzene 
• 68486-17-9 (2-chloro-4-methyl-phenyl)-p-tolyl ether 

Relevant articles and documents

Four- and Sixfold Tandem-Domino Reactions Leading to Dimeric Tetrasubstituted Alkenes Suitable as Molecular Switches

A highly efficient palladium-catalyzed fourfold tandem-domino reaction consisting of two carbopalladation and two C-H-activation steps was developed for the synthesis of two types of tetrasubstituted alkenes 3 and 6 with intrinsic helical chirality starting from substrates 1 and 4, respectively. A sixfold tandem-domino reaction was also developed by including a Sonogashira reaction. 20 compounds with different substitution patterns were prepared with yields of up to 97%. Structure elucidation by X-ray crystallography confirmed helical chirality of the two alkene moieties. Photophysical investigations of some of the compounds showed pronounced switching properties through light-controlled changes of their stereochemical configuration.