767319-38-0

Basic information

• Product Name: (-)-(1Z,2S,3R,4S)-1-ethylidene-2,4-dimethyl-5-oxo-3-((1S)-1-phenylethoxy)-heptyl isobutyrate
• Synonyms: (-)-(1Z,2S,3R,4S)-1-ethylidene-2,4-dimethyl-5-oxo-3-((1S)-1-phenylethoxy)-heptyl isobutyrate
• CAS NO: 767319-38-0
• Molecular Weight: 374.521
• Mol File: 767319-38-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (-)-(1Z,2S,3R,4S)-1-ethylidene-2,4-dimethyl-5-oxo-3-((1S)-1-phenylethoxy)-heptyl isobutyrate(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(1Z,2S,3R,4S)-1-ethylidene-2,4-dimethyl-5-oxo-3-((1S)-1-phenylethoxy)-heptyl isobutyrate(767319-38-0)
• EPA Substance Registry System: (-)-(1Z,2S,3R,4S)-1-ethylidene-2,4-dimethyl-5-oxo-3-((1S)-1-phenylethoxy)-heptyl isobutyrate(767319-38-0)

Safety Data

• Hazardous Substances Data: 767319-38-0(Hazardous Substances Data)

Upstream product

• 767319-35-7 (-)-(1E,3Z)-2-methyl-1-((1S)-1-phenylethoxy)penta-1,3-dien-3-ol isobutyrate 
• 681144-32-1 Trimethyl-{(Z)-1-[(E)-1-methyl-2-((S)-1-phenyl-ethoxy)-vinyl]-propenyloxy}-silane 
• 51425-54-8 (Z)-3-trimethylsiloxy-2-pentene 

Downstream Products

• 1313587-25-5 (1Z,2S,3R,4S,6R,7R)-1-ethylidene-7-hydroxy-2,4,6-trimethyl-5-oxo-3-[(1S)-1-phenylethoxy]octyl isobutyrate 
• 1313587-40-4 (2S,3R)-3-{(4S,5R,6S)-6-[(S,Z)-3-(isobutyryloxy)pent-3-en-2-yl]-2,2,5-trimethyl-1,3-dioxan-4-yl}but-2-yl 4-nitrobenzoate 
• 1313587-39-1 (1Z,2S,3R,4S,6S,7S)-1-ethylidene-7-(4-nitrobenzoyloxy)-2,4,6-trimethyl-5-oxo-3-[(1S)-1-phenylethoxy]octyl isobutyrate 
• 1313587-38-0 (1Z,2S,3S,4R,5R,6R,7S)-1-ethylidene-5-hydroxy-7-(4-nitrobenzoyloxy)-2,4,6-trimethyl-3-[(1S)-1-phenylethoxy]octyl isobutyrate 
• 1313587-34-6 (1Z,2S,3S,4S,5R,6S,7R)-7-acetoxy-1-ethylidene-3-hydroxy-2,4,6-trimethyl-5-[(1S)-1-phenylethoxy]octyl isobutyrate 
• 1313587-33-5 (1Z,2S,3S,4R,5S,6R,7R)-7-acetoxy-1-ethylidene-5-hydroxy-2,4,6-trimethyl-3-[(1S)-1-phenylethoxy]octyl isobutyrate 
• 1313587-30-2 (1Z,2S,3S,4R,5R,6S,7R)-1-ethylidene-5,7-dihydroxy-2,4,6-trimethyl-3-[(1S)-1-phenylethoxy]octyl isobutyrate 
• 1313587-29-9 C₂₅H₃₈O₅ 
• 1313587-28-8 (1Z,2S,3R,4S,6S,7R)-1-ethylidene-7-hydroxy-2,4,6-trimethyl-5-oxo-3-[(1S)-1-phenylethoxy]octyl isobutyrate 
• 767319-54-0 (7Z,4S,5S,6S)-4,6-dimethyl-5-((1S)-1-phenylethoxy)-7-((triethylsilyl)oxy)non-7-en-3-one 
• 767319-58-4 (4S,6S)-4,6-Dimethyl-5-((S)-1-phenyl-ethoxy)-nonane-3,7-dione 
• 767319-24-4 (+)-(2S,3S,4S,5S,6S)-3-ethyl-3,5-dihydroxy-2,4,6-trimethylcyclohexan-1-one 
• 847758-56-9 Isobutyric acid (Z)-(2S,3R,4S)-1-eth-(Z)-ylidene-2,4-dimethyl-3-((S)-1-phenyl-ethoxy)-5-trimethylsilanyloxy-hept-5-enyl ester 

Relevant articles and documents

Expeditious asymmetric synthesis of a stereoheptad corresponding to the C(19)-C(27)-ansa chain of rifamycins: Formal total synthesis of rifamycin S

In the presence of sulfur dioxide and an acid promoter, (-)-(1E,3Z)-2-methyl-1-((1S)-1-phenylethoxy)penta-1,3-dien-3-yl isobutyrate reacts with (Z)-3-(trimethylsilyloxy)-pent-2-ene giving a silyl sulfinate intermediate that undergoes, in the presence of p

First asymmetric synthesis of the cyclohexanone subunit of baconipyrones A and B. Revision of its structure

(Chemical Equation Presented) An asymmetric synthesis of the 3,5-dihydroxycyclohexanone subunit of baconipyrones A and B, as well as that of the hydroxydiketone subunit of baconipyrones C and D ((-)-(4S,6S)-4,6-dimethyl- 5-hydroxynonan-3,7-dione), is desc