769121-30-4

Basic information

• Product Name: tert-butyl 4-(acetylamino)phenylcarbamate
• Synonyms: tert-butyl 4-(acetylamino)phenylcarbamate
• CAS NO: 769121-30-4
• Molecular Formula: C₁₃H₁₈N₂O₃
• Molecular Weight: 250.29362
• Mol File: 769121-30-4.mol
• Article Data: 15

Chemical Properties

• Appearance: /
• CAS DataBase Reference: tert-butyl 4-(acetylamino)phenylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl 4-(acetylamino)phenylcarbamate(769121-30-4)
• EPA Substance Registry System: tert-butyl 4-(acetylamino)phenylcarbamate(769121-30-4)

Safety Data

• Hazardous Substances Data: 769121-30-4(Hazardous Substances Data)

Upstream product

• 24424-99-5 di-tert-butyl dicarbonate 
• 106-50-3 1,4-phenylenediamine 
• 232597-42-1 tert-butyl 4-acetylphenylcarbamate 
• 756483-96-2 tert-butyl 4-acetylphenylcarbamate oxime 
• 71026-66-9 N-(tert-butoxycarbonyl)-1,4-phenylenediamine 
• 108-24-7 acetic anhydride 
• 4248-19-5 tert-butyl carbazate 
• 103-88-8 4-bromoacetanilide 
• 105-53-3 diethyl malonate 
• 122-80-5 N-acetyl-p-phenylenediamine 
• 75-36-5 acetyl chloride 

Downstream Products

• 18144-47-3 tert-butyl 4-aminobenzoate 
• 35008-62-9 4-(N-acetylamino)phenyl isothiocyanate 
• 122-80-5 N-acetyl-p-phenylenediamine 

Relevant articles and documents

Thiazole ring-containing amide compounds as well as preparation method and application thereof

The invention discloses thiazole ring-containing amide compounds as well as a preparation method and application thereof, and belongs to the field of chemical technologies and pesticides. According to the present invention, p-phenylenediamine is adopted as a raw material to synthesize a series of the thiazole ring-containing amide compounds, and the synthesized thiazole ring-containing amide compounds have good inhibition effects on Xanthomonas oryzae pv.Oryza (Xoo), Xanthomonas oryzae pv.Oryzcola (Xoc) and Xanthomonas axonophora pv.Citri (Xac) in agricultural diseases and insect pests, and can be used for preparing the anti-plant bacterium agent.

Zinc(II)-Catalyzed Synthesis of Secondary Amides from Ketones via Beckmann Rearrangement Using Hydroxylamine-O-sulfonic Acid in Aqueous Media

A zinc(II)-catalyzed single-step protocol for the Beckmann rearrangement using hydroxylamine-O-sulfonic acid (HOSA) as the nitrogen source in water was developed. This direct method efficiently produces secondary amides under open atmosphere in a pure form after basic aqueous workup. It isenvironmentally benign and operationally simple.

o-Phthalic Anhydride/Zn(OTf)2 co-catalyzed Beckmann rearrangement under mild conditions

o-Phthalic anhydride/Zn(OTf)2 co-catalyzed Beckmann rearrangement was developed, producing the corresponding amide in up to 99% yield with acid-sensitive functionalities tolerated well, and the scale of the reaction could be enlarged to 77 mmol and the excellent yield was maintained. A successive procedure was developed. Moreover, the reaction was carried out at rt under nearly neutral conditions, and the workup was concise. These features illustrated the potential of the protocol in amide synthesis.