76917-04-9Relevant articles and documents
Metalloporphyrin-Catalyzed Decomposition of Ethyl Azidoformate
Mitani, Michiharu,Takayama, Mimatsu,Koyama, Kikuhiko
, p. 2226 - 2227 (2007/10/02)
Ethyl azidoformate (2) was thermolyzed in the presence of metalloporphyrins.CoTPP accelerated the decomposition rate of 2 and resulted in the preferential formation of the hydrogen-abstraction product (urethane).On the other hand, NiTPP and CuTPP had no influence on the decomposition behavior of 2.