76950-73-7Relevant articles and documents
Revisiting the Reactions of Phenyl(trihalomethyl)mercury with Tetraphenylcyclone (TPCP)
Wang, Hongxing,Gu, Wenxiang,Zhang, Gaoju,Huan, Zhenwei,Cheng, Jin-Pei
, p. 1501 - 1509 (2007/10/03)
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Applications of Phase Transfer Catalysis, VIII. Synthesis and Some Reactions of Tetrasubstituted 6,6-Dihalogenobicyclohex-3-en-2-ones
Steinbeck, Karl,Schenke, Thomas,Runsink, Jan
, p. 1836 - 1844 (2007/10/02)
The reaction of tetrasubstituted cyclopentadienones 1 with dichlorocarbene or dibromocarbene gives specifically the 6,6-dihalogenobicyclohex-3-en-2-ones 2 and 3.Reductive ring opening of 2 or 3 with LiAlH4 cleanly yields the tetrasubstituted 3-halogenophenols 4 and 5.Reaction of 2 or 3 with methylmagnesium iodide leads to 2,4-cyclohexadien-1-ones 13 and to 1-halogeno-5-methylene-1,3-cyclohexadienes 14.