76950-76-0

Basic information

• Product Name: Benzene, 4-(iodomethyl)-1,2-dimethoxy-
• Synonyms: veratryl iodide;4-iodomethyl-1,2-dimethoxybenzene;3,4-Dimethoxybenzyliodid;3,4-dimethoxybenzyl iodide
• CAS NO: 76950-76-0
• Molecular Formula: C9H11IO2
• Molecular Weight: 278.09
• Mol File: 76950-76-0.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzene, 4-(iodomethyl)-1,2-dimethoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 4-(iodomethyl)-1,2-dimethoxy-(76950-76-0)
• EPA Substance Registry System: Benzene, 4-(iodomethyl)-1,2-dimethoxy-(76950-76-0)

Safety Data

• Hazardous Substances Data: 76950-76-0(Hazardous Substances Data)

Upstream product

• 7306-46-9 4-chloromethyl-1,2-dimethoxy-benzene 
• 5763-61-1 3,4-dimethoxybenzylamine 
• 76950-89-5 1-(3,4-Dimethoxy-benzyl)-4,6-diphenyl-1H-pyridine-2-thione 
• 93-03-8 (3,4-dimethoxyphenyl)methanol 
• 120-14-9 3,4-dimethoxy-benzaldehyde 
• 76950-82-8 1-(3,4-Dimethoxy-benzyl)-2-methylsulfanyl-4,6-diphenyl-pyridinium; iodide 

Downstream Products

• 152033-23-3 (2R,5R)-2-(t-Butyl)-5-(3,4-dimethoxybenzyl)-3-methyl-5-(1-methylethyl)-4-oxo-1-imidazolidincarbonsaeure-t-butylester 
• 342043-17-8 (R)-4-(3,4-Dimethoxy-benzyl)-3-((R)-2-methoxy-1-phenyl-ethyl)-oxazolidine-4-carboxylic acid tert-butyl ester 
• 220875-93-4 1-(3,4-dimethoxy-benzyl)-cyclopentanecarboxylic acid methyl ester 
• 743442-96-8 3-(3,4-dimethoxyphenyl)-1-(5-hydroxy-2,2-dimethyl-2H-chromen-6-yl)propan-1-one 
• 220876-06-2 1-(3,4-dimethoxy-benzyl)-cyclopentanecarboxylic acid 
• 123251-05-8 (3R,4R)-3-[(3-methoxy-4-benzyloxyphenyl)methyl]-4-[(3,4-dimethoxyphenyl)methyl] dihydro-2-(3H)-furanone 
• 87605-56-9 (3R,4R)-3-[(3-methoxy-4-hydroxyphenyl)methyl]-4-[(3,4-dimethoxyphenyl)methyl]dihydro-2(3H)-furanone 

Relevant articles and documents

Application of "click" chemistry in solid phase synthesis of alkyl halides

A convenient and highly selective microwave assisted procedure for the conversion of allylic, benzylic and aliphatic alcohols to their corresponding halides using polymer-bound triphenylphosphine and iodine is presented. In case of symmetrical diols, mono-iodination product is obtained in very high yield. Additionally, highly regioselective behavior is observed in our procedure. Simplicity in operation, no column chromatography required for the purification of the products, recyclability of the reagents used, short reaction times and good to excellent yields are the advantages of our protocol. Most functional groups remain unaffected under our reaction condition.

Efficient and selective iodination of benzylic alcohols using NaI/bronsted ionic liquid system at room temperature

A simple, chemoselective, and effective procedure for the conversion of benzylic and allylic alcohols into corresponding iodides using NaI in the presence of a catalytic amount of 3-methylimidazolium hydrogensulfate ([Hmim]+[image omitted]) at room temperature is reported.

Iodination of alcohols using triphenylphosphine/iodine in ionic liquid under solvent-free conditions

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