7697-55-4

Basic information

• Product Name: Cyclohexaneethanol,â-methylene-
• CAS NO: 7697-55-4
• Molecular Weight: 140.225
• Mol File: 7697-55-4.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Cyclohexaneethanol,â-methylene- (CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexaneethanol,â-methylene- (7697-55-4)
• EPA Substance Registry System: Cyclohexaneethanol,â-methylene- (7697-55-4)

Safety Data

• Hazardous Substances Data: 7697-55-4(Hazardous Substances Data)

Upstream product

• 2157-18-8 isopropenylcyclohexane 
• 593-71-5 Chloroiodomethane 
• 2719-27-9 cyclohexanylcarbonyl chloride 
• 7697-61-2 2-cyclohexylacrylaldehyde 
• 2163-44-2 diethyl 2-cyclohexylmalonate 
• 823-76-7 Cyclohexyl methyl ketone 
• 3070-72-2 2-cyclohexylacrylic acid methyl ester 
• 931-51-1 cyclohexylmagnesiumchloride 
• 107-19-7 propargyl alcohol 
• 108-94-1 cyclohexanone 
• 1552-92-7 ethyl cyclohexylideneacetate 
• 5452-75-5 ethyl 2-cyclohexylacetate 
• 5664-21-1 cyclohexylacetaldehyde 
• 108-85-0 1-bromocyclohexane 

Downstream Products

• 74963-03-4 ((S)-2-Cyclohexyl-oxiranyl)-methanol 
• 74963-03-4 ((R)-2-Cyclohexyl-oxiranyl)-methanol 
• 162086-78-4 (3-bromoprop-1-en-2-yl)cyclohexane 
• 866487-74-3 2-(2-cyclohexyl-allyl)-isoindole-1,3-dione 
• 105359-25-9 (3SR,4SR,5SR)-2-cyclohexyl-5,6-epoxy-4-hydroxy-6-methyl-3-methylthiohept-1,5-diene 
• 105359-21-5 (2S,2'R,3'R)-3'-(1-Cyclohexyl-vinyl)-3,3-dimethyl-[2,2']bioxiranyl 
• 162086-79-5 2-cyclohexyl-1-methylthioprop-2-ene 
• 33204-54-5 (R)-(-)-2-cyclohexyl-2-butanol 
• 1192887-53-8 (R)-ethyl 5-formyl-5-cyclohexyl-4,5-dihydro-1H-pyrazole-3-carboxylate 
• 1232828-81-7 benzyl 2-cyclohexylprop-2-en-1-yl sulfide 
• 1415610-54-6 2-cyclohexylallyl ethyl carbonate 
• 136578-48-8 ethyl 3-cyclohexyl-3-butenoate 

Relevant articles and documents

Copper-Catalyzed Enantiotopic-Group-Selective Allylation of gem-Diborylalkanes

We report a copper-catalyzed enatiotopic-group-selective allylation of gem-diborylalkanes with allyl bromides. The combination of copper(I) bromide and H8-BINOL derived phosphoramidite ligand proved to be the most effective catalytic system to provide various enantioenriched homoallylic boronate esters, containing a boron-substituted stereogenic center that is solely derived from gem-diborylalkanes, in good yields with high enantiomeric ratios under mild conditions. Experimental and theoretical studies have been conducted to elucidate the reaction mechanism, revealing how the enatiotopic-group-selective transmetalation of gem-diborylalkanes with chiral copper complex occurs to generate chiral α-borylalkyl-copper species for the first time. Additional synthetic applications to the synthesis of various chiral building blocks are also included.

Intramolecular Remote C-H Activation via Sequential 1,4-Palladium Migration to Access Fused Polycycles

An unprecedented intramolecular remote C-H activation via sequential 1,4-palladium migration with an aromatic ring as a conveyor has been described. This reaction provides an efficient route to construct diverse polycyclic frameworks in moderate to good yield via palladium-catalyzed remote C-H activation/alkene insertion, arylation, alkenylation, and the Heck reaction. The preliminary mechanistic studies revealed that the 1,4-palladium migration process was reversible.

Enantioselective bromocyclization of allylic amides catalyzed by BINAP derivatives

A highly enantioselective bromocyclization of allylic amides with N-bromosuccinimide (NBS) was developed with DTBM-BINAP as a catalyst, affording chiral oxazolines with a tetrasubstituted carbon center in high yield with up to 99% ee. By utilizing the bro