77144-79-7Relevant articles and documents
Electrochemical-Induced Hydroxysulfonylation of α-CF3 Alkenes to Access Tertiary β-Hydroxysulfones
Luo, Xu,Wang, Shengchun,Lei, Aiwen
, p. 1016 - 1022 (2022/02/07)
An electrochemical hydroxysulfonylation of α-CF3 alkenes was accomplished in this work. By using easily available sodium sulfinates as the sulfonylating agents, a series of valuable α-trifluoromethyl tertiary alcohols were synthesized under mild and environmentally friendly electrolysis conditions in moderate to good yields. The preliminary mechanistic investigation indicates that this difunctional reaction involves a radical process via a sulfonyl radical. Gram-scale synthesis shows the significant potential application of this protocol. (Figure presented.).
Electrochemical synthesis of β-hydroxy-, β-alkoxy-, and β-carbonyloxy sulfones by vicinal difunctionalization of olefins
Zhang, Zhefan,Yan,Ma, Dengke,Sun, Jianwei
supporting information, p. 1509 - 1511 (2019/05/04)
An electrochemical vicinal heterodifunctionalization of olefins for the synthesis of β-oxysulfones is described. With suitable choice of the conditions, including current, electrodes, and electrolyte, this oxidation reaction proceeded efficiently in an un
Son, Soobin,Shyam, Pranab K.,Park, Hyowon,Jeong, Ilgyo,Jang, Hye-Young
, p. 3365 - 3371 (2018/07/13)
