77192-27-9

Basic information

• Product Name: 1,3-Nonadiene, (Z)-
• CAS NO: 77192-27-9
• Molecular Formula: C9H16
• Molecular Weight: 124.226
• Mol File: 77192-27-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,3-Nonadiene, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Nonadiene, (Z)-(77192-27-9)
• EPA Substance Registry System: 1,3-Nonadiene, (Z)-(77192-27-9)

Safety Data

• Hazardous Substances Data: 77192-27-9(Hazardous Substances Data)

Upstream product

• 110210-28-1 5,5-bis(benzenesulfonyl)nonane 
• 865-47-4 potassium tert-butylate 
• 75-65-0 tert-butyl alcohol 
• 129058-88-4 (Z)-3-Nonenyl acetate (Z)-3-Nonenyl acetate (Z)-3-Nonenyl acetate (Z)-3-nonenyl acetate 
• 83927-51-9 (1S,3S,7R)-3-Pentyl-4-thia-tricyclo[5.2.1.0^2,6]dec-8-ene 4,4-dioxide 

Downstream Products

• 1215227-05-6 (E)-4-vinylnon-2-ene 
• 53786-93-9 1,4-undecadiene 
• 4567-98-0 dimethyl undecanedioate 
• 56305-42-1 (E)-1-phenyldec-4-en-1-one 
• 1215227-10-3 (Z)-4-vinylnon-2-ene 

Relevant articles and documents

Mixed metal bases as promoters of 1,4-eliminations

When treated with the LIDAKOR mixture, allyl type ethers very readily undergo 1,4-elimination to afford conjugated dienes (3 - 73). In typical cases, the reaction is brought about stereo- and regioselectively (2 and 7, respectively). Under suitable conditions, lithium dimethylamide or even lithium diisopropylamide adds to the dienes generated in situ thus leading to a variety of new allyl amines (5-8).

A HIGHLY STEREOSELECTIVE SYNTHESIS OF (E)-1- SUBSTITUTED-1,3-DIENES.

(E)-1-substituted-1,3-dienes are obtained with high selectivity by the thermal extrusion of SO2 from 2-substituted-2,5-dihidrothiophene-1,1-dioxides generated by a retro Diels-Alder reaction.An application to the synthesis of (E)-9,11-dodecadien-1-yl acetate, a sex pheromone of the red-bollworm moth is described.