77232-13-4

Basic information

• Product Name: 2-p-tolyl-pyrimidine
• Synonyms: 2-p-tolyl-pyrimidine
• CAS NO: 77232-13-4
• Molecular Weight: 170.214
• Mol File: 77232-13-4.mol
• Article Data: 22

Chemical Properties

• Melting Point: 90 °C
• CAS DataBase Reference: 2-p-tolyl-pyrimidine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-p-tolyl-pyrimidine(77232-13-4)
• EPA Substance Registry System: 2-p-tolyl-pyrimidine(77232-13-4)

Safety Data

• Hazardous Substances Data: 77232-13-4(Hazardous Substances Data)

Upstream product

• 21139-61-7 2-(4-methylphenyl)-4,6-dichloropyrimidine 
• 1722-12-9 2-chloropyrimidine 
• 696-61-7 4-tolylmagnesium chloride 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 90252-89-4 p-tolylzinc(II) chloride 
• 5720-05-8 4-methylphenylboronic acid 
• 289-95-2 PYRIMIDINE 
• 14080-23-0 2-cyanopyrimidine 
• 192887-48-2 p-MeC₆H₄-MnCl 
• 624-31-7 4-tolyl iodide 
• 5158-46-3 methylzinc chloride 
• 7431-45-0 2-phenylpyrimidine 
• 2975-46-4 3-(trimethylsilyl)prop-2-yn-1-al 
• 6326-27-8 p-methylbenzamidine hydrochloride 

Downstream Products

• 77232-37-2 2-(4-Bromomethyl-phenyl)-pyrimidine 
• 1101187-26-1 C₁₇H₂₀N₂O₂ 
• 1200124-03-3 2-(2,6-dichloro-4-methylphenyl)pyrimidine 
• 1217189-15-5 2-(2,6-dichloro-4-methylphenyl)pyrimidine 
• 1242673-17-1 5-methyl-2-(pyrimidin-2-yl)phenyl acetate 
• 1217189-16-6 2-(2,6-dibromo-4-methylphenyl)pyrimidine 
• 1391997-60-6 2-(4-tolyl)-3,4-dihydropyrimidine 
• 1436430-36-2 tetraethyl 2,2′-(5-methyl-2-(pyrimidin-2-yl)-1,3-phenylene)dimalonate 
• 1446325-95-6 2-(5-methyl-2-(pyrimidin-2-yl)phenyl)isoindoline-1,3-dione 
• 1446325-96-7 C₂₇H₁₆N₄O₄ 
• 1373917-20-4 5-methyl-2-pyrimidin-2-ylbenzonitrile 

Relevant articles and documents

Heterogeneous gold(I)-catalyzed cyclization between ynals and amidines: An efficient and practical synthesis of 2,4-disubstituted pyrimidines

A novel and highly efficient heterogeneous gold(I)-catalyzed cyclization between ynals and amidines has been developed that proceeds smoothly under mild conditions and provides a general and practical method for the synthesis of a wide variety of 2,4-disu

Selective Methylation of Arenes: A Radical C?H Functionalization/Cross-Coupling Sequence

A selective, nonchelation-assisted methylation of arenes has been developed. The overall transformation, which combines a C?H functionalization reaction with a nickel-catalyzed cross-coupling, offers rapid access to methylated arenes with high para selectivity. The reaction is amenable to late-stage methylation of small-molecule pharmaceuticals.

Ruthenium-catalyzed double-fold C-H tertiary alkoxycarbonylation of arenes using di-tert-butyl dicarbonate

An efficient ruthenium-catalyzed double-fold C-H alkoxycarbonylation of arenes was developed using di-tert-butyl dicarbonate as the tertiary esterification reagent, which leads to a direct route to valuable 2,6-dicarboxylated products. This journal is