77234-00-5Relevant articles and documents
Vanadium-substituted wells-Dawson heteropolyacid as catalyst for liquid phase oxidation of 1,4-dihydropyridine derivative
Sanchez, Laura M.,Sathicq, Angel G.,Baronetti, Graciela T.,Thomas, Horacio J.,Romanelli, Gustavo P.
, p. 172 - 180 (2014)
H7P2W17VO62.25H2O Wells-Dawson heteropolyacid was prepared, characterized and evaluated as catalyst in a 1,4-dihydropyridine oxidation reaction. The optimal conditions are the following: 1 mmol% of HW
MnOx/catechol/H2O: A cooperative catalytic system for aerobic oxidative dehydrogenation of N-heterocycles at room temperature
Tang, Tao,Bi, Xiuru,Meng, Xu,Chen, Gexin,Gou, Mingxia,Liu, Xiang,Zhao, Peiqing
, (2019/12/09)
Amorphous manganese oxide doped by Na+ ion (Na-AMO) was successfully prepared and found to be an efficient heterogeneous catalyst in aerobic oxidative dehydrogenation of N-heterocycles, cooperate with catechol. Na-AMO was fully characterized by XRD, XPS BET H2-TPR, CO2-TPD FT-IR, TEM, SEM and had rich amounts of surface absorbed active oxygen species which are responsible for superior catalytic performance. The synergistic interaction between Na-AMO and catechol makes catalytic system efficient and tolerant, which offers various N-heterocycles in good to excellent yields under mild conditions.
One-pot synthesis of 3-hydroxy-2-oxindole-pyridine hybrids via Hantzsch ester formation, oxidative aromatization and sp3 C–H functionalization using FeWO4 nanoparticles as recyclable heterogeneous catalyst
Paplal, Banoth,Nagaraju, Sakkani,Sathish, Kota,Kashinath, Dhurke
, p. 110 - 115 (2017/10/16)
Synthesis of poly-substituted 3-hydroxy-2-oxindole-pyridine hybrids is reported via sp3 C–H bond functionalization as key steps using FeWO4 nanoparticles as reusable heterogeneous catalyst. Formation of Hantzsch ester (DHP) followed by aromatization, and sp3 C–H bond functionalization was achieved using FeWO4 nanoparticles (20 mol%) at 80 °C. Temperature dependent reactivity was observed for mono aldol (at 80 °C) and bis aldol (at 120 °C) products. The catalyst was regenerated and reused up to 6 cycles without losing catalytic activity. The FeWO4 nanoparticles were also used for oxidative aromatization of different DHP derivatives and for the sp3 C–H functionalization of 2-methyl pyridine.