77547-13-8

Basic information

• Product Name: (2E,6E,12Z)-14-Benzenesulfonyl-9-(1-chloro-1-methyl-ethyl)-2,6,12-trimethyl-tetradeca-2,6,12-trienoic acid methyl ester
• Synonyms: (2E,6E,12Z)-14-Benzenesulfonyl-9-(1-chloro-1-methyl-ethyl)-2,6,12-trimethyl-tetradeca-2,6,12-trienoic acid methyl ester
• CAS NO: 77547-13-8
• Molecular Weight: 495.123
• Mol File: 77547-13-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2E,6E,12Z)-14-Benzenesulfonyl-9-(1-chloro-1-methyl-ethyl)-2,6,12-trimethyl-tetradeca-2,6,12-trienoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2E,6E,12Z)-14-Benzenesulfonyl-9-(1-chloro-1-methyl-ethyl)-2,6,12-trimethyl-tetradeca-2,6,12-trienoic acid methyl ester(77547-13-8)
• EPA Substance Registry System: (2E,6E,12Z)-14-Benzenesulfonyl-9-(1-chloro-1-methyl-ethyl)-2,6,12-trimethyl-tetradeca-2,6,12-trienoic acid methyl ester(77547-13-8)

Safety Data

• Hazardous Substances Data: 77547-13-8(Hazardous Substances Data)

Upstream product

• 25996-10-5 (Z)-neryl bromide 
• 106-25-2 Nerol 
• 56881-52-8 (Z)-(3,7-dimethylocta-2,6-diene-1-sulfonyl)benzene 
• 67517-28-6 methyl (2E,6E)-8-chloro-2,6-dimethyl-2,6-octadienoate 

Downstream Products

• 77547-15-0 (2E,6E)-8-((1S,3R)-3-Benzenesulfonylmethyl-4-chloro-2,2,4-trimethyl-cyclohexyl)-2,6-dimethyl-octa-2,6-dienoic acid methyl ester 
• 77547-16-1 (2E,6E)-8-((1S,5S)-5-Benzenesulfonylmethyl-4,6,6-trimethyl-cyclohex-3-enyl)-2,6-dimethyl-octa-2,6-dienoic acid methyl ester 
• 77547-17-2 [(1S,5S)-5-((2E,6E)-8-Bromo-3,7-dimethyl-octa-2,6-dienyl)-2,6,6-trimethyl-cyclohex-2-enylmethanesulfonyl]-benzene 
• 77547-18-3 (3E,7E)-(1S,11S)-10-Benzenesulfonyl-4,8,12,15,15-pentamethyl-bicyclo[9.3.1]pentadeca-3,7,12-triene 

Relevant articles and documents

SYNTHESIS OF TRANS-4,8,12,15,15-PENTAMETHYLBICYCLOPENTADECA-3E,7Z,12Z-TRIENE, A GEOMETRICAL ISOMER OF ANHYDROVERTICILLOL

A 7Z-isomer of anhydroverticillol skeleton was constructed in 15 percent yield when the 7E allyl bromide having secoverticillol framework was treated with LiN(TMS)2.Reductive removal of the SO2Ph group furnished a geometrical isomer of anhydroverticillol.