77802-37-0Relevant articles and documents
Branch-Selective and Enantioselective Iridium-Catalyzed Alkene Hydroarylation via Anilide-Directed C-H Oxidative Addition
Grélaud, Simon,Cooper, Phillippa,Feron, Lyman J.,Bower, John F.
supporting information, p. 9351 - 9356 (2018/08/07)
Tertiary benzylic stereocenters are accessed in high enantioselectivity by Ir-catalyzed branch selective addition of anilide ortho-C-H bonds across styrenes and α-olefins. Mechanistic studies indicate that the stereocenter generating step is reversible.