7783-26-8Relevant articles and documents
Syntheses and Molecular Structures of Liquid Pyrophoric Hydridosilanes
B?hme, Uwe,Franze, Georg,Friebel, Mike,Gerwig, Maik,Gründler, Franziska,Kroke, Edwin,Rosenkranz, Marco,Schmidt, Horst
, p. 762 - 773 (2020/08/05)
Trisilane, isotetrasilane, neopentasilane, and cyclohexasilane have been prepared in gram scale. In-situ cryo crystallization of these pyrophoric liquids in sealed capillaries on the diffractometer allows access to the single crystal structures of these c
Synthesis of polysilanes by tunneling reactions of H atoms with solid Si2H6 at 10K
Sogoshi, Norihito,Sato, Shoji,Takashima, Hideaki,Sato, Tetsuya,Hiraoka, Kenzo
, p. 986 - 987 (2012/09/22)
Tunneling reactions of H atoms with solid Si2H6 at 10K were investigated. The in situ and real-time reactions H + Si 2H6 to form silane and polysilanes were monitored using FT-IR. Quantitative analysis of gaseou
Diagnostics of the gas-phase thermal decomposition of Si2H6 using vacuum ultraviolet photoionization
Tonokura, Kenichi,Murasaki, Tetsuya,Koshi, Mitsuo
, p. 507 - 511 (2008/10/08)
Vacuum ultraviolet (VUV) photoionization at 10.2 eV was employed for the detection of gas-phase molecules formed after thermal decomposition of disilane at a total pressure of 30 Torr and in the temperature range of 298-740 K. The SinH2(n+1) (n=3-5) and SinH2n (n=2-5) species resulting from disilane pyrolysis in a flow reactor were directly observed using time-of-flight mass spectrometry. Unlike multiphoton ionization at 6.4 eV photons, no fragmentation was observed by the VUV single-photon ionization at 10.2 eV.