77855-67-5Relevant articles and documents
Syntheses with organoboranes. X. Monohydroboration of conjugated enynes with catecholborane catalyzed by nickel(II) chloride complexes with diphosphines
Zaidlewicz, Marek,Meller, Jerzy
, p. 1049 - 1056 (1999)
The monohydroboration of representative conjugated enynes - but-1-en-3-yne (1), 2-methylbut-1-en-3-yne (2), pent-3-en-1-yne (3), hex-1-en-3-yne (4), 2-methyl-4-phenyl-but-1-en-3-yne (5), 4-methyl-1-phenylpent-3-en-1-yne (6) and 1-ethynylcyclohex-1-ene (7)
Palladium catalysed tandem cyclisation-anion capture. Part 8: Cascade hydrostannylation-cyclisation-anion capture and cascade hydroboration-cyclisation-anion capture on solid phase
Grigg, Ronald,MacLachlan, William S,MacPherson, David T,Sridharan, Visuvanathar,Suganthan, Selvaratnam
, p. 10335 - 10345 (2007/10/03)
Up to four bonds and five stereocentres are created, in five component processes (five point diversity), utilising resin bound aryl iodides by hydroboration or hydrostannylation of alkynes, followed by cyclisation-anion capture involving Suzuki or Stille reactions. Three small libraries were prepared to validate the chemistry.
