77874-89-6

Basic information

• Product Name: 3-(Methoxycarbonyl)-2,2,6,6-tetramethyl-4-oxo-1-piperidinyloxy
• Synonyms: 3-(Methoxycarbonyl)-2,2,6,6-tetramethyl-4-oxo-1-piperidinyloxy;3-(Methoxycarbonyl)-2,2,6,6-tetramethyl-4-oxo-
• CAS NO: 77874-89-6
• Molecular Formula: C₁₁H₁₈NO₄
• Molecular Weight: 228.26492
• Product Categories: Heterocycles;Intermediates;Spin Labeling Compounds
• Mol File: 77874-89-6.mol
• Article Data: 2

Chemical Properties

• Melting Point: 52-60°C
• Appearance: /
• Storage Temp.: Refrigerator
• Solubility: Chloroform (Sparingly), Methanol (Slightly)
• CAS DataBase Reference: 3-(Methoxycarbonyl)-2,2,6,6-tetramethyl-4-oxo-1-piperidinyloxy(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(Methoxycarbonyl)-2,2,6,6-tetramethyl-4-oxo-1-piperidinyloxy(77874-89-6)
• EPA Substance Registry System: 3-(Methoxycarbonyl)-2,2,6,6-tetramethyl-4-oxo-1-piperidinyloxy(77874-89-6)

Safety Data

• Hazardous Substances Data: 77874-89-6(Hazardous Substances Data)

Usage

Chemical Properties

Yellow to Orange Solid

Upstream product

• 45985-26-0 4-oxo-2,2,6,6-tetramethylpiperidin-oxyl 
• 186581-53-3 diazomethane 
• 124-38-9 carbon dioxide 

Downstream Products

• 770706-85-9 C₁₉H₂₉N₂O₃ 
• 748767-02-4 C₁₉H₂₉N₂O₃ 
• 733736-65-7 C₁₉H₂₉N₂O₃ 
• 757939-41-6 C₁₉H₂₉N₂O₃ 
• 864150-34-5 C₁₉H₂₉N₂O₃ 
• 583827-08-1 (3R,4R)-4-[(1'S)-phenylethyl]amino-3-methoxycarbonyl-2,2,6,6-tetramethyl-piperidine-1-oxyl hydrochloride 
• 583827-08-1 (3R,4R)-4-[(1'R)-phenylethyl]amino-3-methoxycarbonyl-2,2,6,6-tetramethyl-piperidine-1-oxyl hydrochloride 
• 583827-08-1 (3S,4S)-4-[(1'R)-phenylethyl]amino-3-methoxycarbonyl-2,2,6,6-tetramethyl-piperidine-1-oxyl hydrochloride 
• 948915-97-7 C₃₆H₆₀N₅O₈ 
• 948915-91-1 C₃₇H₆₂N₅O₈ 
• 948915-96-6 C₂₉H₄₉N₄O₇ 
• 948915-90-0 C₃₀H₅₁N₄O₇ 
• 948915-95-5 C₂₂H₃₈N₃O₆ 
• 948915-89-7 C₁₈H₃₂N₃O₄ 

Relevant articles and documents

4-Amino-1-oxyl-2,2,6,6-tetramethylpiperidine-3-carboxylic acid (β-TOAC), the first spin-labelled, cyclic, chiral β-amino acid resolved in an enantiomerically pure state

Amination of 3-carboxymethyl-1-oxyl-2,2,6,6-tetramethyl-4-piperidone with (R)-α-methylbenzylamine, NaBH3CN reduction of the resulting enamine and removal of the chiral auxiliary from the separated diastereoisomers, led to enantiomerically pure