77946-89-5

Basic information

• Product Name: 1,3-Dimethoxy-2-(trifluoromethyl)-1,3,4,4,5,5,5-heptafluoro-1-pentene
• Synonyms: 1,3-Dimethoxy-2-(trifluoromethyl)-1,3,4,4,5,5,5-heptafluoro-1-pentene
• CAS NO: 77946-89-5
• Molecular Weight: 324.118
• Mol File: 77946-89-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3-Dimethoxy-2-(trifluoromethyl)-1,3,4,4,5,5,5-heptafluoro-1-pentene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dimethoxy-2-(trifluoromethyl)-1,3,4,4,5,5,5-heptafluoro-1-pentene(77946-89-5)
• EPA Substance Registry System: 1,3-Dimethoxy-2-(trifluoromethyl)-1,3,4,4,5,5,5-heptafluoro-1-pentene(77946-89-5)

Safety Data

• Hazardous Substances Data: 77946-89-5(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 1584-03-8 perfluoro-2-methylpent-2-ene 

Downstream Products

• 593-53-3 Methyl fluoride 
• 84047-25-6 (Z)-4,4,5,5,5-Pentafluoro-3-methoxy-2-trifluoromethyl-pent-2-enoyl fluoride 
• 53352-88-8 pentafluoropropionyl(trifluoromethyl)ketene 

Relevant articles and documents

Synthesis of perfluorinated dialkyl ethers from products of reaction of hexafluoropropene dimers with methanol

Perfluoro-2-methyl-2-pentene reacts with methanol in tetrahydrofuran and acetone in the presence of KOH to form predominantly the product of fluorine substitution at the double bond, whereas perfluoro-4-methyl-2-pentene reacts with methanol on heating in tetrahydrofuran in the presence of KOH or triethylamine with incorporation of two or three methoxy groups. Gas-phase fluorination of 3-methoxyperfluoro-2-methyl-2-pentene and 3-methoxyperfluoro-2-methylpentane with elemental fluorine on catalysts is studied, and conditions for preparing perfluoro-2-methyl-3-methoxypentane are revealed.