77949-40-7

Basic information

• Product Name: formiate de methyl-2 butene-3 ol-2
• Synonyms: formiate de methyl-2 butene-3 ol-2
• CAS NO: 77949-40-7
• Molecular Weight: 114.144
• Mol File: 77949-40-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: formiate de methyl-2 butene-3 ol-2(CAS DataBase Reference)
• NIST Chemistry Reference: formiate de methyl-2 butene-3 ol-2(77949-40-7)
• EPA Substance Registry System: formiate de methyl-2 butene-3 ol-2(77949-40-7)

Safety Data

• Hazardous Substances Data: 77949-40-7(Hazardous Substances Data)

Upstream product

• 64-18-6 formic acid 
• 556-82-1 3-methyl-2-buten-1-ol 
• 115-18-4 2-methyl-3-buten-2-ol 

Relevant articles and documents

CONDENSATIONS BIOMIMETIQUES: EDIFICATION DE SQUELETTES TERPENIQUES A PARTIR DE SYNTHONS ISOPRENIQUES

The action of perchloric, trifluoroacetic and formic acids on the 1,1-(and 3,3-) dimethylallylic alcohols has been studied.In the presence of formic acid in dichloromethane 2-methyl-3-butene-2-ol (DMVC) has been condensed on the acetate of 3-methyl-3-butene-1-ol (IPA) giving geranylic and lavandulylic type 1,1-adducts.Saponification, dehydration, oxidation and isomerisation of the former type lead to citral.In the same medium, DMVC produces (after saponification) a C10 glycol which upon dehydration produces lavandulol in a convenient way.Geraniol and its acetate have been condensed with low yield on IPA giving farnesylic derivatives.