78227-45-9

Basic information

• Product Name: trans-1-(1'-chloro-1'-phenyltrimethyldisilanyl)propene
• Synonyms: trans-1-(1'-chloro-1'-phenyltrimethyldisilanyl)propene
• CAS NO: 78227-45-9
• Molecular Weight: 254.907
• Mol File: 78227-45-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-1-(1'-chloro-1'-phenyltrimethyldisilanyl)propene(CAS DataBase Reference)
• NIST Chemistry Reference: trans-1-(1'-chloro-1'-phenyltrimethyldisilanyl)propene(78227-45-9)
• EPA Substance Registry System: trans-1-(1'-chloro-1'-phenyltrimethyldisilanyl)propene(78227-45-9)

Safety Data

• Hazardous Substances Data: 78227-45-9(Hazardous Substances Data)

Upstream product

• 16136-85-9 trans-1-Chloropropen 
• 4235-65-8 tris(trimethylsilyl)phenylsilane 

Relevant articles and documents

Photolysis of Organopolysilanes. Reaction of Trimethylsilylphenylsilylene with Functional-Group-Substituted Olefins

The photolysis of tris(trimethylsilyl)phenylsilane (1) in the presence of vinyl chloride or 1-bromo-2-methylpropene afforded, probably via silacyclopropane intermediates, the respective 1-alkenyl-1-halo-1-phenyltrimethyldisilanes in moderate yields.Photolysis of 1 in the presence of cis- and trans-1-chloropropene proceeded with high stereospecificity to give cis- and trans-1-(chlorodisilanyl)propene, respectively.Irradiation of 1 in the presence of ethyl vinyl ether afforded 1-methoxy-1-phenyl-1-vinyltrimethyldisilane after methanolysis of the photolysis product.Similar irradiation of 1 in the presence of ethyl vinyl ether, followed by treatment with hydrogen chloride, gave 1-chloro-1-(1'-ethoxyethyl)-1-phenyltrimethyldisilane and 1-chloro-1-(2'-ethoxyethyl)-1-phenyltrimethyldisilane.Irradiation of 1 with cis- and trans-1-methoxy-1-hexene, followed by ethanolysis, produced the corresponding cis- and trans-1-(ethoxydisilanyl)-1-hexene with high stereospesificity.Irradiation of 1 with vinyl acetate gave directly 1-acetoxy-1-phenyl-1-vinyltrimethyldisilane.