783-79-9Relevant articles and documents
Efficient copper-catalyzed trifluoromethylation of aromatic and heteroaromatic iodides: The beneficial anchoring effect of borates
Gonda, Zsombor,Kovacs, Szabolcs,Weber, Csaba,Gati, Tamas,Meszaros, Attila,Kotschy, Andras,Novak, Zoltan
supporting information, p. 4268 - 4271 (2014/09/30)
Efficient copper-catalyzed trifluoromethylation of aromatic iodides was achieved with TMSCF3 in the presence of trimethylborate. The Lewis acid was used to anchor the in situ generated trifluoromethyl anion and suppress its rapid decomposition. Broad applicability of the new trifluoromethylating reaction was demonstrated in the functionalization of different aromatic and heteroaromatic iodides.
Efficient synthesis of [18F]trifluoromethane and its application in the synthesis of PET tracers
Van Der Born, Dion,Herscheid,Orru, Romano V.A.,Vugts, Danielle J.
supporting information, p. 4018 - 4020 (2013/07/26)
A new strategy towards [18F]trifluoromethyl-containing compounds is developed. [18F]trifluoromethane is synthesised in a fast and efficient manner and subsequently used in the reaction with aldehydes and ketones forming [18/sup
Substituent effects. XIX. Solvolysis of 1-aryl-1-(trifluoromethyl)ethyl tosylates
Murata,Goto,Fujiyama,Mishima,Fujio,Tsuno
, p. 1129 - 1137 (2007/10/02)
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