78335-07-6Relevant articles and documents
Insertion of a two sulfur unit into the S-S bond - Tailor-made polysulfides
Rys,Harpp
, p. 7169 - 7172 (2000)
Triphenylthiosulfenyl chloride (1) reacts with disulfides RSSR, yielding tetrasulfides as the main products. The results of the insertion for different R groups are reported. A two-step mechanism involving the formation of unsymmetrical trisulfide intermediates containing the trityl group is proposed. (C) 2000 Elsevier Science Ltd.