78389-98-7Relevant articles and documents
Synthesis of allenes by palladium-catalyzed SN2′ reaction of indium organometallics with propargylic esters
Riveiros, Ricardo,Sestelo, Jose Perez,Sarandeses, Luis A.
, p. 3595 - 3598 (2008/09/19)
Allenes have been efficiently prepared by the reaction of propargylic esters (benzoates, acetates, carbonates) with triorganoindium compounds (R 3In) under palladium catalysis, via an SN2′ rearrangement. The reaction proceeds smoothl